Concept explainers
(a)
Interpretation:
The
Concept Introduction:
For a spontaneous reaction, the value for
Answer to Problem 25.36AP
Explanation of Solution
The given reaction is:
This reaction is the addition of two reactions that are shown below:
Thus, the
+
_____________________________________________________________________
(b)
Interpretation:
The equilibrium constant (at
Concept Introduction:
The relation between
Answer to Problem 25.36AP
Explanation of Solution
The relation between
By substituting the value of
Thus, the equilibrium constant for the temperature
(c)
Interpretation:
A structural reason for the reaction being so favorable, is to be suggested.
Concept Introduction:
Overall reaction is said to be favorable when the products are more stable than the reactants.
Answer to Problem 25.36AP
This reaction is favorable because the overall conversion is from a less stable thioester to a more stable oxoester.
Explanation of Solution
This reaction is favorable because the overall conversion is from a thioester to a more stable ester.
This reaction is favorable because the overall conversion is from a thioester to a more stable ester.
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Chapter 25 Solutions
Organic Chemistry
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