(a)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The conversion of an
(b)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The
(c)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The reaction of an alkene with ozone leads to the formation of a cyclic compound called molozonide or primary ozonide. The molozonide consist of two peroxy linkage which is quite unstable. It rearranges rapidly, at low temperature and forms an ozonide. These ozonides are often unstable. They react with reducing agent like zinc or dimethyl sulphide and forms
(d)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: Osmium tetraoxide or osmic acid with
(e)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The oxidative cleavage of an alkene by hot concentrated
(f)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: A solution of peroxyacetic acid in water is preferably used for anti dihydroxylation of alkenes. The mechanism proceeds through formation of epoxide followed by of anti addition of
(g)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The hydrogenation of an alkene is done by
(h)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The reaction of an alkene with
(i)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The reaction of an alkene with
(j)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The reaction of bromine in the presence of water with an alkene results Markonikov orientation, anti-stereochemistry and no rearrangement.
(k)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The halogenation reaction of an alkene with chlorine results anti-stereochemistry addition of chlorine.
(l)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The reaction of an alkene with
(m)
To determine: The structure of the expected product when limonene reacts with the given reagent in excess amount.
Interpretation: The structure of the expected product when limonene reacts with the given reagent in excess amount is to be stated.
Concept introduction: The mixture of
Want to see the full answer?
Check out a sample textbook solutionChapter 8 Solutions
Organic Chemistry (9th Edition)
- 9. Give the product structure and the mechanism for the reaction of diethyl carbonate with ethyl 3-phenylpropionate reacted sequentially with a. sodium ethoxide in ethanol. b. sodium hydroxide. c. aqueous acid. d. heat.arrow_forwardWhat will be the major product if 1-hexanol is oxidized with pyridinium chlorochromate in dichloromethane as the solvent? Select one: A. hexanone B. hexanoic acid C. hexanal D. propyl propanoate What is the minor product obtained when (Z)-1-bromo-2-methylbut-1-ene reacts with HBr? Select one: A. 1,2-dibromo-2-methylbutane B. 2,2-dibromo-1-methylbutane C. 1,2-dibromo-1-methylbutane D. 1,1-dibromo-2-methylbutanearrow_forwardProvide the structural formula of the products that are formed when acetophenone reacts with these reagents: 1. NaBH4 in Methanol 2. Ag(NH3)2+ 3. C6H5MgBr, then H3O+ 4. H2 in Pt 5. Hydroxylamine 6. Phenylhydrazine 7. LiAlH4 then water 8. HCN 9. Diethylamine 10. 2 CH3OH, HCl catalystarrow_forward
- Benzene is often produced as a side product during Grignard reactions using phenylmagnesium bromide. How can its formation be explained? Give a balanced equation for its formation.arrow_forwardNameand Draw the structures of all possible chemical (Electrophilic aromatic substitution) reactions of the o-propylbenzaldehyde a. Halogenation (Chlorination or Bromination) b. Nitration c. Sulphonation d. Friedel Craft Alkylation e. Friedel Craft Acylationarrow_forwardWhat are the major products from the reaction of methyl butanoate with diisobutylaluminum hydride at negative seventy- eight degrees Celsius, followed by acidic work-up? a. butanal and methanol b. butanal and ethanol c. butanoate and methane d. butyric acid and methanol e. butanoate and hydrogen gas a C e O farrow_forward
- Which of the following compounds can be used to synthesize ethanoicpropanoic anhydride (CH;COOOCCH½CH3)? A. CH;COCI+ CH;CH2COO`Na* → B. CH;COOH +heat → C. CH3CH2CH2COCI + CH;COO Na* → D. A and Carrow_forwardWhich of the following compounds would be used to prepare the alkene shown below by the Wittig reaction? A. cyclohexyl bromide/propanal B. cyclohexanone/ethyl bromide C. cyclohexyl bromide/isopropyl bromide D. cyclohexanone/ethanalarrow_forwardFrom which starting materials can the product formed as a result of the following reaction be synthesized? A. Acetophenone and butanal B. Benzaldehyde and 3-pentanone C. Benzaldehyde and 2-pentanone D. Acetophenone and 2-butanonearrow_forward
- Define what is reduction reaction, reducing agents, weak and strong reducing agents sodium borohydride reduction with benzophenone and sodium borohyride to get benzophenonearrow_forward1. Write a chemical equation depicting how trans-1-phenyl-2-(4- chlorophenyl)-ethene can be synthesized from benzaldehyde and an appropriate alkyl halide.arrow_forwardWhat reaction produces the following compound in good yield? a. Ethanoyl chloride + phenol in pyridineb. Acetic acid + phenol and sulfuric acidc. Acetic acid + benzened. Ethane + Sodium PhONa (Phenoxide) + Hot Sulfuric Acidarrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningMacroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole