Concept explainers
(a)
Interpretation:
Among molecules mentioned in the question, it is to be determined which has shorter
Concept introduction:
Hybridization affects both bond length and bond strength. The two
Answer to Problem 3.27P
Explanation of Solution
The structure of the molecules mentioned in the question is shown below:
The two
In the first molecule, according to VSEPR theory, the
In the second molecule, according to VSEPR theory, the
This shows that in the first molecule, the percentage s character in
Bond length and bond strength is determined from the hybridization involved in the molecule.
(b)
Interpretation:
Among the molecules mentioned in the question, it is to be determined which has shorter
Concept introduction:
Hybridization affects both bond length and bond strength. The two
Answer to Problem 3.27P
Explanation of Solution
The structure of the molecules mentioned in the question is shown below:
The two
In the first molecule, according to VSEPR theory, the
In the second molecule, according to VSEPR theory, the
This shows that in the first molecule, the percentage s character in C-N bond is more than that in the second molecule. Therefore, the C-N bond is shorter and stronger in the first molecule.
Bond length and bond strength is determined from the hybridization involved in the molecule.
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Chapter 3 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
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