Concept explainers
(a)
Interpretation: The name and structure of the alcohols which on oxidation gives following product
Concept introduction:
Alcohols are the hydrocarbons which have
Alcohols can be of three types on the basis of degree of carbon atom to which the
Primary alcohol: The
Secondary alcohol: The
Tertiary alcohol: The
If a strong oxidizing agent is used, the oxidation of primary alcohol gives carboxylic acid.
A weaker oxidizing or partial oxidation of primary alcohol gives aldehydes.
While secondary alcohols always give ketones on oxidation.
(b)
Interpretation: The name and structure of the alcohols which on oxidation gives following product 2-hexanone
Concept introduction:
Alcohols are the hydrocarbons which have
Alcohols can be of three types on the basis of degree of carbon atom to which the
Primary alcohol: The
Secondary alcohol: The
Tertiary alcohol: The
If a strong oxidizing agent is used, the oxidation of primary alcohol gives
A weaker oxidizing or partial oxidation of primary alcohol gives aldehydes.
While secondary alcohols always give
Want to see the full answer?
Check out a sample textbook solutionChapter 23 Solutions
Chemistry & Chemical Reactivity
- 1. (a) Draw the structures of the eight isomeric pentyl alcohols, C3H11OH. (b) Name each by the IUPAC system and by the carbinol system. (c) Label each as primary, secondary, or tertiary, (d) Which one is isopentyl alcohol? tert-Pentyl alcohol? (e) Give the structure of a primary, a secondary, and a tertiary alcohol of the formula C,H13OH.arrow_forwardThe ester with the formula C8H16O2 gives an alcohol and an acid when hydrolyzed. When the alcohol is isolated and oxidized, it forms a ketone. Which of these formulas cannot be the ester?arrow_forwardA certain hydrocarbon has a molecular formula of C5H8. Which of the following is not a structural possibility for this hydrocarbon: (d) It contains an alkyne O It contains one ring and one double bond (c) It contains two double bonds and no rings O (b) It contains one ring and no double bondsarrow_forward
- 5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acidarrow_forwardWrite two complete, balanced equations for each of the following reactions, one using condensed formulas and one using Lewis structures:(a) ethanol reacts with propionic acid(b) benzoic acid, C6H5CO2H, is added to a solution of sodium hydroxidearrow_forwardGlucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.arrow_forward
- (B) Draw a structural diagram for each of the following organic compounds: (a) 2-ethyl-4-methyl-2-pentanol (b) 1,2-ethandiol (c) 1,3-dimethylbenzenearrow_forwardIdentify which of the following statement(s) is/are true. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic acid is C2H4O2.arrow_forwardWrite a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction.(Use condensed structural formula) (A) Ozonolysis of 3,3-Dimethyloct-4-yne(B) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne(C) Partial hydrogenation using Lindlar’s Catalyst 2,2,5,5-Tetramethylhex-3-ynearrow_forward
- The IUPAC name for a carboxylic acid is based on thename of the hydrocarbon with the same number of carbonatoms. The ending -oic is appended, as in ethanoic acid,which is the IUPAC name for acetic acid. Draw the structureof the following acids: (a) methanoic acid, (b) pentanoicacid, (c) 2-chloro-3-methyldecanoic acid.arrow_forwardGive the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:arrow_forwardWrite a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction.(Use condensed structural formula) (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene(c) Reaction of (4E)-2,4-Dimethylhexa-1,4-diene with a mole of waterarrow_forward
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning