Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
Book Icon
Chapter 14.7, Problem 14.13P

(a)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In a condensation reaction, two molecules join together to form a large molecule with the removal of small molecule such as water.

(b)

Interpretation Introduction

To determine: The formation of the given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson reaction.

(c)

Interpretation Introduction

To determine: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols.

Interpretation: The formation of given ether in good yield by condensation of the corresponding alcohol and the alternative method for the ether that cannot be prepared by the condensation of the alcohols is to be identified.

Concept introduction: In alkoxymercuration-demercuration, ether is produced when alkene reacts with an alcohol in the presence of mercury acetate.

Blurred answer
Students have asked these similar questions
Show how to convert cyclohexanol to these compounds. a. Cyclohexene b. Cyclohexane c. Cyclohexanone d. Bromocyclohexane
10. What product(s) would result from the oxidation of each of the following alcohols with, for example, potassium permanganate? If no reaction occurs, write N.R. a. 2-Butanol b. 2-Methyl-2-hexanol c. Cyclohexanol d. 1-Methyl-1-cyclopentanol
Starting with cyclohexanone, show how to prepare these compounds. In addition to the given starting material, use any other organic or inorganic reagents as necessary. a. Cyclohexanol b. Cyclohexene c. cis-1,2-Cyclohexanediol d. 1-Methylcyclohexanol e. 1-Methylcyclohexene f. 1-Phenylcyclohexanol g. 1-Phenylcyclohexene h. Cyclohexene oxide i. trans-1,2-Cyclohexanediol

Chapter 14 Solutions

Organic Chemistry (9th Edition)

Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305580350
    Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning