Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Draw the line-angle formula of the enol formed in the following alkyne hydration reaction and then draw the
structural formula of the carbonyl compound with which this enol is in equilibrium.
-C=CH
1. (sia)2BH
2. NaOH/H₂O₂
an enol
carbonyl compound
• You do not have to consider stereochemistry.
• Draw both the enol and the carbonyl forms.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom
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ChemDoodleⓇ
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5A
In the following reactions, mixtures of alkenes and ethyl ethers
are formed. Draw their structures. Explain which is or are likely
to be the main product(s) in each reaction. In case of formation
of two isomers of alkenes, explain which is formed in greater
proportion
CH3
ofi
H3C-
-Br
CH3
EtOH
Ethers can be prepared by reaction of an alkoxide or phenoxide ion with a primary alkyl halide.
Draw the structure of the expected organic product of the reaction of 1-iodo-2-methylpropane with the following alkoxide ic
+
O Na
You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• Do not include lone pairs in your answer. They will not be considered in the grading.
• Do not include counter-ions, e.g., Na", I", in your answer.
C
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Chapter 13 Solutions
Organic Chemistry - Standalone book
Ch. 13.2 - Based on Hammonds postulate which holds that the...Ch. 13.3 - Prob. 2PCh. 13.3 - Using : O =N+= O : as the electrophile, write a...Ch. 13.4 - Prob. 4PCh. 13.5 - Prob. 5PCh. 13.6 - Prob. 6PCh. 13.6 - Write a reasonable mechanism for the formation of...Ch. 13.6 - tert-Butylbenzene can be prepared by alkylation of...Ch. 13.6 - Prob. 9PCh. 13.7 - The reaction shown gives a single product in 88...
Ch. 13.7 - Prob. 11PCh. 13.8 - Using benzene and any necessary organic or...Ch. 13.10 - Prob. 13PCh. 13.11 - Prob. 14PCh. 13.12 - Prob. 15PCh. 13.12 - Prob. 16PCh. 13.13 - Prob. 17PCh. 13.13 - Prob. 18PCh. 13.14 - Reaction of chlorobenzene with p-chlorobenzyl...Ch. 13.15 - Prob. 20PCh. 13.15 - Prob. 21PCh. 13.15 - Prob. 22PCh. 13.16 - Prob. 23PCh. 13.16 - Prob. 24PCh. 13.17 - Prob. 25PCh. 13.18 - Prob. 26PCh. 13.19 - Write the structure of the expected product from...Ch. 13.20 - Prob. 28PCh. 13.20 - Prob. 29PCh. 13.21 - Prob. 30PCh. 13.21 - Offer an explanation for the observation that...Ch. 13.21 - Prob. 32PCh. 13 - Write the structure of the organic product in each...Ch. 13 - Prob. 34PCh. 13 - Prob. 35PCh. 13 - Prob. 36PCh. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Treatment of the alcohol shown with sulphuric acid...Ch. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Arrange the following five compounds in order of...Ch. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - Give reagents suitable for carrying out each of...Ch. 13 - Prob. 49PCh. 13 - Prob. 50PCh. 13 - Which is the best synthesis of the compound shown?Ch. 13 - What combination of acyl chloride or acid...Ch. 13 - A standard synthetic sequence for building a...Ch. 13 - Prob. 54PCh. 13 - Prob. 55PCh. 13 - Prob. 56PCh. 13 - Prob. 57PCh. 13 - Prob. 58PCh. 13 - Prob. 59PCh. 13 - Prob. 60DSPCh. 13 - Prob. 61DSPCh. 13 - Prob. 62DSPCh. 13 - Prob. 63DSP
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- Ethers can be prepared by reaction of an alkoxide or phenoxide ion with a primary alkyl halide. Draw the structure of the expected organic product of the reaction of iodomethane with the following alkoxide ion: CH3 H3C O Na You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • Do not include counter-ions, e.g., Na", I, in your answer. орy вste ChemDoodlearrow_forwardThe 2-propenyl cation appears to be a primary carbocation, and yet it is considerably more stable than a 1° carbocation such as the 1-propyl cation. CH,=CH-CH, CH, CH, CH," 2-Propenyl cation 1-Propyl cation How would you account for the differences in the stability of the two carbocations?arrow_forwardWrite an equation for the acid-base reaction between 2,4-pentanedione and sodium eth- oxide and calculate its equilibrium constant, K. The pK, of 2,4-pentanedione is 9; that of ethanol is 15.9. CH,CCHÖCH, + CH,CH,O Na* H 2,4-Pentanedione Sodium ethoxidearrow_forward
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