The strongest bond has to be identified from C=O bond in an ester (1735 cm -1 ) or the C=O bond in a saturated ketone (1715 cm -1 ). Concept introduction: Spectroscopy: It is study of the interaction of matter and electromagnetic radiation, a continuum of different types of electromagnetic radiation each associated with a particular energy range makes up the electromagnetic spectrum. IR frequency (cm -1 ): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz). Stretch vibrations: It is a vibration occurring along the line of the bond a stretching vibration changes the bond length. Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle. Given information: The IR value is given below,

Question

Shown below is a carbocation intermediate in an electrophilic addition reaction of HCl with an alkene. For the conformation shown, select each hydrogen whose bond to carbon is aligned for effective hyperconjugation with the vacant p orbital on the positively charged carbon. Each adjacent carbon will have only one C-H bond so aligned. • Gray = C; white = H; red = 0; blue = N; dark green = Cl; brown =Br; light green =F; purple = I; yellow = S; orange = P. • Double click to select atoms. • You can zoom in and out using the mouse scroll wheel (or pinch to zoom on touch screens).

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Question

Chapter 12.SE, Problem 38AP

Interpretation Introduction

Interpretation:

The strongest bond has to be identified from C=O bond in an ester (1735 cm^-1) or the C=O bond in a saturated ketone (1715 cm^-1).

Concept introduction:

Spectroscopy:

It is study of the interaction of matter and electromagnetic radiation, a continuum of different types of electromagnetic radiation each associated with a particular energy range makes up the electromagnetic spectrum.

IR frequency (cm^-1):

It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Stretch vibrations:

It is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations:

It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Given information:

The IR value is given below,

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