EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 12.4, Problem 11ATS
Interpretation Introduction
Interpretation:
The given reaction is the conversion of
Concept introduction:
It is done by calculating the oxidation state of the atoms. If there is an increase in the charge on any atom, it is said to be oxidized. If there is a decrease in the oxidation state of the atom, it is said to be reduced. The oxidation state of the carbon on which the change has occurred must be calculated by cleaving the bonds between carbon and the atom to which it is attached.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
I2 (aq) + CH3COCH3 (aq) HI (aq) + ICH2COCH3 (aq)Iodine in solution has a yellow-brown color, whereas the acetone and both products are colorless. This means that we can run the reaction using iodine as the limiting reagent, and when we see that the yellow-brown color of the iodine has disappeared, we know that the reaction has stopped and all of the iodine has been consumed.
Recall that to calculate a rate of reaction, we would like toknow the change in concentration of a reactant or product during a fixed amount of time. Wewill choose the reactant iodine in this case, because its brown color allows us to determinewhen its concentration has fallen to zero.
Rate = –Δ[I2] / Δt = – ([I2]final – [I2]initial) / ([tfinal – tinitial) = – (0 – [I2]initial) / (tfinal – 0) = [I2]initial / tfinal
Run several trials at different concentrations of reactants and use themethod of initial rates to obtain values for k, x, y, and z in the rate law.
Rate = k [I2]x [acetone]y [H+]z
Run the…
82. The space shuttle Orbiter utilizes the oxidation of methylhy-
drazine by dinitrogen tetroxide for propulsion:
4N₂H3CH3(1) + 5N₂O4 (1) 12H₂O(g) + 9N₂(g) + 4CO2(8)
Calculate AH for this reaction.
▬▬▬▬▬▬▬▬▬▬
8.
With refrence to the reaction observation below, write down the structural formula of X, Y
and Z. Write equation when Y react with Iodine in basic medium, Tollens reagent and
hydroxylamine.
Chapter 12 Solutions
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
Ch. 12.1 - Prob. 1LTSCh. 12.1 - Prob. 1PTSCh. 12.1 - Prob. 2ATSCh. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.3 - Prob. 8CCCh. 12.3 - Prob. 9CCCh. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 10PTSCh. 12.4 - Prob. 11ATS
Ch. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 12PTSCh. 12.4 - Prob. 13ATSCh. 12.6 - Prob. 14CCCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 15PTSCh. 12.6 - Prob. 16PTSCh. 12.7 - Prob. 18CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 19PTSCh. 12.9 - Prob. 20ATSCh. 12.9 - Prob. 21CCCh. 12.10 - Prob. 7LTSCh. 12.10 - Prob. 22PTSCh. 12.10 - Prob. 23ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 24PTSCh. 12.13 - Prob. 25ATSCh. 12.13 - Prob. 26CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 27PTSCh. 12.13 - Prob. 28ATSCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Prob. 32PPCh. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Prob. 35PPCh. 12 - Prob. 36PPCh. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51PPCh. 12 - Prob. 52PPCh. 12 - Prob. 53ASPCh. 12 - Prob. 54ASPCh. 12 - Prob. 55ASPCh. 12 - Prob. 62IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - Prob. 66IPCh. 12 - Prob. 67IPCh. 12 - Prob. 68IPCh. 12 - Prob. 69IPCh. 12 - Prob. 74IP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which of the following compounds have the same oxidation level as the compound in row 1? (Enter your answer in numerical order as the row number(s) separated by commas, i.e. 2,3,5. If none of the compounds have the same oxidation level, write 'none'.) First set Second set Row 1 Row 2 NH2 OH Row 3 Br NH2 Row 4 NH2 Row 5 Br First set: Second set:arrow_forwardHow much free energy is released under standard conditions when electrons are passed from succinate to ubiquinone? Note: The Faraday constant F = 23.1 kcal/(mole x volt) A) About 0.069 kcal/mol B) About 54 kcal/mol C) About 35 kcal/mol D) About 1.6 kcal/mol E) None of the above, energy is required for electrons to flow from succinate to ubiquinonearrow_forwardAlkaloids are basic nitrogen-containing compounds of plant origin, many of which are physiologically active when administered to humans. Ingestion of coniine, isolated from water hemlock, can cause weakness, labored respiration, paralysis, and eventually death. Coniine is the toxic substance in the “poison hemlock” used in the death of Socrates. In small doses, nicotine is an addictive stimulant. In larger doses, it causes depression, nausea, and vomiting. In still larger doses, it is a deadly poison. Solutions of nicotine in water are used as insecticides. Cocaine is a central nervous system stimulant obtained from the leaves of the coca plant.Classify each amino group in these alkaloids according to type (primary, secondary, tertiary, aliphatic, aromatic, heterocyclic).arrow_forward
- help mearrow_forwarde discuss SN1arrow_forwardbipyridine)3]2* in its ground state and in an excited state. Compared to the ground state, the molecule in its excited state is a hv stronger oxidant and weaker reductant. stronger oxidant and stronger reductant. weaker oxidant and weaker reductant. weaker oxidant and stronger reductant.arrow_forward
- 1) Find AH for the synthesis of B₂H6, diborane: 2B(s) + 3H2(g) → B₂H6(g) Given: 2 B(s) + 1/2O2(g) → B2O3(s) B₂H6(g) + 3 O2(g) →B2O3(s) + 3 H₂O(g) H2(g) + 1/2O2(g) → H₂O(1) H₂O(1)→ H₂O(g) AH₁ = -1273 kJ/mole AH₂=-2035 kJ/mole AH3= -286 kJ/mole 44 kJ/mole AH4=arrow_forward: Draw the product of this reaction. Ignore inorganic byproducts. 1. NaNHz Drawing Version: 1.142.0 + production Atoms, Bonds and Rings | NH₂ 1 OH 1 CI 1arrow_forwardPropose two molecular formulas for each of the following molecular ions: (a) 72; (b) 100; (c) 73.arrow_forward
- Benzene is one of the compounds used as octane enhancers in unleaded gasoline. It is manufactured by the catalytic conversion of acetylene to benzene: 3C2H2 (8) C6H6 (8). Which value of Kwould make this reaction most useful commercially? K 0.01, K1, or K 10. Explain your answer.arrow_forwardClassify each of the following reactions:? CH4(g)+2O2(g)→CO2(g)+2H2O(g) 2NaClO3(s)→2NaCl(s)+3O2(g) S(s)+3F2(g)→SF6(g) 2Na(s)+H2O(l)→2NaOH(aq) 2N2O5(g)→4NO2(g)+O2(g)arrow_forward1) Compound 3-chlorobenzoic acid can be prepared from methylbenzene through a two- steps reaction. chemical equations for the reactions ? 2) 2 C12 (g) + 2 H20 (g) = 4 HCI (g) + 02 (g) Ac 2 HCI (g) + 1/2 02 (g) = C12 (g) + H20 (g) Ac' relationship between Ac and Ac' ? 3) Hydrogen iodide, HI decomposes 2HI (g) = H2 (g) + 12 (g) AH < 0 -2.00 atm of HI placed in a glass - allowed to reach equilibrium a) Ap for the reaction if 30.0% of HI decomposes ? b) the concentration of HI(g) will increase, decrease or remain the same when the temperature of reaction is increased ?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning