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(a)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but the arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
(b)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but the arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the rate of reaction depends only on one reactant, which is involved in reaction is called unimolecular nucleophilic substitution reaction.
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
(c)
Interpretation:
The product of stereoisomers that formed in the given reaction should be given.
Concept introduction:
Isomer:
The compound is having same molecular formula but the arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the rate of reaction depends only on one reactant, which is involved in reaction is called unimolecular nucleophilic substitution reaction.
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
(d)
Isomer:
The compound is having same molecular formula but the arrangement of the atom is different is called isomer.
In the nucleophilic substitution reaction, the rate of reaction depends only on one reactant, which is involved in reaction is called unimolecular nucleophilic substitution reaction.
In
The rate determination step is formation of carbocation.
The stability order of carbocation is,
Tertiary > Secondary > Primary
Therefore, tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation. Primary alcohol is less stable therefore it won’t undergoes
In the nucleophilic substitution reaction, the rate of reaction depends on reactant as well as nucleophile, which are involved in reaction is called bimolecular nucleophilic substitution reaction.
In
Reactant and nucleophile are present at the rate determination step.
The order of species involving in
Tertiary < Secondary < Primary
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Chapter 11 Solutions
Organic Chemistry
- Draw a structural formula for the major organic product of the following reaction: CH2Cl2 Cl2 Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If enantiomers are formed, just draw one. орy вste ChemDoodlearrow_forwardWhat stereoisomers are formed when pent-1-ene is treated with H2O and H2SO4?arrow_forwardDraw the alkene reactant of the following reaction. n 6 H3o+ H3C OH H20arrow_forward
- Draw a structural formula for the major product of the reaction shown. -CH₂CH3 Br₂ H₂O • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer.arrow_forwardDraw a structural formula for the major product of the reaction shown. Cl2 H20 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. орy aste [F ChemDoodle Previousarrow_forwardWhich compounds (I-IV) form a set of stereoisomers?arrow_forward
- Draw the alkene that would react with the reagent given to account for the product formed. ? + HCI CH3 CH3CCH3 CI • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. #[ ] در ChemDoodlearrow_forwardWhich of the following exists in mainly the enol tautomeric form? 요 H3C H3C CH3 i H3C IV || CH 3 EtO H3C ||| OEt OEtarrow_forwardWhat is the major product for | the following reaction? * ÇH3 CH;C-CH=CH, + HCI major product , 3-chloro-2,2-dimethylpentane 2-chloro-2,3-dimethylbutane 3-chloro-2,2-dimethylpropane 3-chloro-2,2-dimethylbutane 3-chloro-2,3-dimethylpentane 2-chloro-2,3-dimethylpentane 2-chloro-3,4-dimethylbutane 2-chloro-2,2-dimethylbutanearrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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