Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Chapter 11.3, Problem 11.15P
(a)
To determine
Whether the derivation for the commutation relation
(b)
To determine
The implications obtained by sandwich the commutator,
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The coordinates of unit a, of the atoms in a body-centered cubic lattice are (0,0,0), (0,1,0), (0,0,1), (0,1,1), (1,0,0), (1,1,0), (1,0,1), (1,1,1) and (1/2;1/2,1/2). Calculate the structure factors Fhkl when all the atoms are identical
Estimate kBT at room temperature, and convert this energy into electronvolts (eV). Using this result, answer the following:
(a) Would you expect hydrogen atoms to be ionized at room temperature? (The binding energy of an electron in a hydrogen atom is 13.6 eV.)
(b) Would you expect the rotational energy levels of diatomic molecules to be excited at room temperature? (It costs about 10-4 eV to promote such a system to an excited rotational energy level.)
4.3 Neon (Ne) is a crystalline solid with an FCC structure. The interatomic energy per atom can be
written as:
20 [(12.13)(=) - (14.45()*] (eV / ate
atom)
U(R)=28
Where & and σ are constants that depend on the polarizability, and mean dipole moment, and
the extent of overlap of core electrons. For crystalline Ne, ε = 3.121 x 103 eV and
o = 0.274 nm.
(a) Show that the equilibrium separation between the atoms in an inert gas crystal is given
by ro= (1.090). What is the equilibrium interatomic separation in the Ne crystal?
(b) Find the bonding energy per atom in solid Ne.
(c) Calculate the density of solid Ne (atomic mass = 20.18 g/mol)
Chapter 11 Solutions
Introduction To Quantum Mechanics
Ch. 11.1 - Prob. 11.1PCh. 11.1 - Prob. 11.2PCh. 11.1 - Prob. 11.3PCh. 11.1 - Prob. 11.4PCh. 11.1 - Prob. 11.5PCh. 11.1 - Prob. 11.6PCh. 11.1 - Prob. 11.7PCh. 11.1 - Prob. 11.8PCh. 11.1 - Prob. 11.9PCh. 11.3 - Prob. 11.10P
Ch. 11.3 - Prob. 11.11PCh. 11.3 - Prob. 11.12PCh. 11.3 - Prob. 11.13PCh. 11.3 - Prob. 11.14PCh. 11.3 - Prob. 11.15PCh. 11.3 - Prob. 11.16PCh. 11.4 - Prob. 11.17PCh. 11.5 - Prob. 11.18PCh. 11.5 - Prob. 11.19PCh. 11.5 - Prob. 11.20PCh. 11.5 - Prob. 11.21PCh. 11.5 - Prob. 11.22PCh. 11 - Prob. 11.23PCh. 11 - Prob. 11.24PCh. 11 - Prob. 11.25PCh. 11 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Prob. 11.29PCh. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.35PCh. 11 - Prob. 11.36PCh. 11 - Prob. 11.37P
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