8. a) Draw out the products for the following epoxide formation reaction. b) Do these reactions involve rearrangements? c) What are the important factors you must remember when performing this reaction? MCPBA H₂O*
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- In the presence of light or heat, diazomethane (CH,N2) creates a carbene, which then adds to an alkene to make a cyclopropane. In the boxes below. draw the mechanism arrows for the reaction. H INEN: INE N:For the following dehydrohalogenation (E2) reaction, draw the major organic product(s), including stereochemistry CI (Cн Сок СH, HII (Cн, СОн4) Draw the complete electron-pushing arrow mechanism for the following reductions. Explain, using resonance contributors, the regiochemistry that results in each case. ỌMe Na, MeOH ? NH3 CHO Na, MeOH ? NH3
- As we will learn, many antioxidants–compounds that prevent unwanted radical oxidation reactions from occurring–are phenols, compounds that contain an OH group bonded directly to a benzene ring.a.) Explain why homolysis of the O–H bond in phenol requiresconsiderably less energy than homolysis of the O–H bond in ethanol(362 kJ/mol vs. 438 kJ/mol).b.) Why is the C–O bond in phenol shorter than the C–O bond in ethanol?Draw the favored product(s) of the following reactions (organic chemistry)4. What are the products obtained from the following elimination reaction? Indicate the major product. CH;CH2CCH3 H2O CI 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH3 Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.
- Identify the major product of the following reaction sequence. 1) [H*], H₂NNH2, (-H₂O) 2) KOH/H₂O, heat HO₂C HO₂C HO CO,H OH OH There is no reaction under these conditions or the correct product is not listed here.For each reaction, decide whether substitution or elimination (or both) is possible, andpredict the products you expect. Label the major products. chlorocyclohexane + NaOCH3 in CH3OHWhich is true of a free energy diagram for an SN1 eaction? It shows one transition state. It always shows that the reaction is net exothermic. It never shows intermediates. It always shows that the reaction is net endothermic. It always includes multiple energy barriers.
- Draw a detailed, step-wise mechanism for the reaction shown below. SHOW ALL BOND-FORMING AND BOND-BREAKING STEPS. SHOW ALL INTERMEDIATES. 1) NaOH 2) H3O* H3C H3C HO5. Draw the major product of the following reactions. Classify each reaction as substitution, elimination, or addition. Indicate if there are any rearrangement products. If the reaction does not proceed, explain why. H₂O, H* HO OH 1) Hg(OAc)2 2) NaBH4 H3PO4 H₂SO4, 100 °C 1) BH3*THF 2) HOOH, -OH CI NaN3 (1 equiv) THF5. Draw the major product of the following reactions. Classify each reaction as substitution, elimination, or addition. Indicate if there are any rearrangement products. If the reaction does not proceed, explain why. 1) BH3 THF 2) HOOH, OH CI NaN3 (1 equiv) THF