An Introduction to Physical Science
14th Edition
ISBN: 9781305079137
Author: James Shipman, Jerry D. Wilson, Charles A. Higgins, Omar Torres
Publisher: Cengage Learning
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Textbook Question
Chapter 12.6, Problem 12.7CE
Is PCl3 ionic or covalent in bonding? What about MgF2?
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(4) Predict the structure of CsCl. Given: radius of Cs+= 0.160 nm, radius of Cl-=0.181nm.
Calculate the radius ratio between Cs+ and Cl- and derive the coordination number
(CN) based on the table below.
Rcation/Ranion
CN
0-0.155
2
3
0.155-0.225
0.225-0.414
0.414-0.732
0.732-1
1
4
6
8
12
(b) Explain different types of carbon nanotubes and
their properties depending on their chirality
Given that the radius of the Ca2+ and F- ions are 1.03 Å and 1.36 Å, respectively, show that the packing fraction of the CaF2 (Fluorite) structure is 0.61.
Chapter 12 Solutions
An Introduction to Physical Science
Ch. 12.1 - Prob. 1PQCh. 12.1 - Prob. 2PQCh. 12.1 - Prob. 12.1CECh. 12.2 - Prob. 1PQCh. 12.2 - Prob. 2PQCh. 12.2 - Find the formula mass of hydrogen sulfide, H2S,...Ch. 12.2 - Prob. 12.3CECh. 12.3 - Prob. 1PQCh. 12.3 - Prob. 2PQCh. 12.4 - Prob. 1PQ
Ch. 12.4 - Prob. 2PQCh. 12.4 - Prob. 12.4CECh. 12.4 - Prob. 12.5CECh. 12.5 - Prob. 1PQCh. 12.5 - Prob. 2PQCh. 12.5 - Prob. 12.6CECh. 12.6 - Is PCl3 ionic or covalent in bonding? What about...Ch. 12.6 - Prob. 12.8CECh. 12.6 - Boron trifluoride, BF3, is an exception to the...Ch. 12.6 - Prob. 1PQCh. 12.6 - Prob. 2PQCh. 12 - Prob. AMCh. 12 - Prob. BMCh. 12 - Prob. CMCh. 12 - Prob. DMCh. 12 - Prob. EMCh. 12 - Prob. FMCh. 12 - Prob. GMCh. 12 - Prob. HMCh. 12 - Prob. IMCh. 12 - Prob. JMCh. 12 - Prob. KMCh. 12 - Prob. LMCh. 12 - Prob. MMCh. 12 - Prob. NMCh. 12 - Prob. OMCh. 12 - Prob. PMCh. 12 - Prob. QMCh. 12 - Prob. RMCh. 12 - Prob. SMCh. 12 - Prob. 1MCCh. 12 - Prob. 2MCCh. 12 - Prob. 3MCCh. 12 - Prob. 4MCCh. 12 - Prob. 5MCCh. 12 - Prob. 6MCCh. 12 - Prob. 7MCCh. 12 - Prob. 8MCCh. 12 - Prob. 9MCCh. 12 - Prob. 10MCCh. 12 - Sodium reacts with a certain element to form a...Ch. 12 - Prob. 12MCCh. 12 - Prob. 13MCCh. 12 - Carbon is a Group 4A element. How many covalent...Ch. 12 - How many shared pairs of electrons are in an...Ch. 12 - Prob. 16MCCh. 12 - Prob. 17MCCh. 12 - Prob. 18MCCh. 12 - Prob. 1FIBCh. 12 - Prob. 2FIBCh. 12 - Prob. 3FIBCh. 12 - Prob. 4FIBCh. 12 - Prob. 5FIBCh. 12 - Prob. 6FIBCh. 12 - Prob. 7FIBCh. 12 - The formula of an ionic compound of a Group 1A...Ch. 12 - Prob. 9FIBCh. 12 - Prob. 10FIBCh. 12 - Prob. 11FIBCh. 12 - Prob. 12FIBCh. 12 - Prob. 1SACh. 12 - Prob. 2SACh. 12 - Prob. 3SACh. 12 - Prob. 4SACh. 12 - Prob. 5SACh. 12 - Prob. 6SACh. 12 - Prob. 7SACh. 12 - Prob. 8SACh. 12 - Prob. 9SACh. 12 - Prob. 10SACh. 12 - Prob. 11SACh. 12 - Prob. 12SACh. 12 - Prob. 13SACh. 12 - Prob. 14SACh. 12 - Prob. 15SACh. 12 - Prob. 16SACh. 12 - Prob. 17SACh. 12 - Prob. 18SACh. 12 - Prob. 19SACh. 12 - Prob. 20SACh. 12 - Prob. 21SACh. 12 - Prob. 22SACh. 12 - Prob. 23SACh. 12 - Prob. 24SACh. 12 - Prob. 25SACh. 12 - A covalent bond in which the electron pair is...Ch. 12 - Could a molecule composed of two atoms joined by a...Ch. 12 - Explain how a polyatomic ion such as carbonate...Ch. 12 - Prob. 29SACh. 12 - Prob. 30SACh. 12 - Prob. 31SACh. 12 - State the short general principle of solubility,...Ch. 12 - Prob. 33SACh. 12 - Prob. 1VCCh. 12 - You decide to have hot dogs for dinner. In the...Ch. 12 - Why cant we destroy bothersome pollutants by just...Ch. 12 - Prob. 3AYKCh. 12 - When you use a bottle of vinegar-and-oil salad...Ch. 12 - Prob. 5AYKCh. 12 - Prob. 6AYKCh. 12 - Prob. 1ECh. 12 - An antacid tablet weighing 0.942 g contained...Ch. 12 - Calculate (to the nearest 0.1 u) the formula mass...Ch. 12 - Calculate (to the nearest 0.1 u) the formula mass...Ch. 12 - Find the percentage by mass of Cl in MgCl2 if it...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Write the Lewis symbols and structures that show...Ch. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Referring only to a periodic table, give the...Ch. 12 - Referring only to a periodic table, give the...Ch. 12 - Prob. 23ECh. 12 - Draw the Lewis structure for formaldehyde, H2CO, a...Ch. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Use arrows to show the polarity of each bond in...Ch. 12 - Use arrows to show the polarity of each bond in...Ch. 12 - Prob. 31ECh. 12 - Prob. 32E
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- The rotational constant of 12C160 2 (from Raman spectroscopy) is 11.70 GHz. What is the CO bond length in themolecule?arrow_forwardThe Madelung constant for the NaCl structure may be found by summing an infinite alternating series of terms giving the electrostatic potential energy between an Na+ ion and its 6 nearest Cl neighbors, its 12 next-nearest N+ neighbors, and so on (see Fig. 12.1a). (a) From this expression, show that the first three terms of the infinite series for the Madelung constant for the NaCl structure yield = 2.13. (b) Does this infinite series converge rapidly? Calculate the fourth term as a check.arrow_forwardThe measured density of a CsCl crystal is 3.988 g/cm3. What is the equilibrium separate distance of Cs+ and Cl- ions?arrow_forward
- The measured density of a NaF crystal is 2.558 g/cm3 . What is the equilibrium separate distance of Na+ and Flions?arrow_forwardThe electron affinity of Cl is 3.61 eV whereas the ionization energy of K is 4.34 eV. How far apart must two molecules be for the KC1 molecule to accumulate enough Coulomb energy to outpace the energy required to create the K+ and (I-) ions?arrow_forwardAn excited state electronic configuration for the valence shell of Na₂ (sodium dimer) is (4µg 3s)¹(4µµ 3s)¹. What are the possible term symbols corresponding to this configuration, including the label for parity? Choose all term symbols that could result for this configuration. о 3{u 1{g 30g о 1 пи 38g 1{uarrow_forward
- 11. a) Determine which planes in an fcc structure have the highest density of atoms. b) Evaluate this density in atoms/cm² for Cu. 12. Repeat Problem 11 for Fe, which has a bcc structure. 13. Show that the maximum packing ratio in the diamond structure is n/3/16. [Hint: The structure may be viewed as two interpenetrating fcc lattices, arranged such that each atom is surrounded by four other atoms, forming a regular tetrahedron.]arrow_forwardSuppose one electron in H2 is excited from the s1s MO to the s1*s MO. Would youexpect the H atoms to remain bonded to each other, or would the molecule fall apart?arrow_forward-Using the following ionic radii, calculate the void volume fraction in the CsCl.arrow_forward
- The energy between a pair of atoms with respect to their distance r can be described by the Lennard-Jones potential: VLJ(r) = 4ɛ 12 [9¹-9] r 6 e a) For € = 0.5 eV, and σ= 0.2 nm, calculate the bond length [Hint: The math is much easier if you keep the units as eV and nm]. b) Show that the bond energy is equal to epsilon.arrow_forward(c) Find the total numbe of symmetry elements in each of the fourteen Bravais latticearrow_forwardAt the zone boundary, what is the reason ?to create the energy gaparrow_forward
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