Which of the following is correct for the H-N-H bond angles in N₂H4 and NH4'? OH-N-H bond angle in NH4 < H-N-H bond angle in N₂H₂ OH-N-H bond angle in NH4H-N-H bond angle in N₂H₂ OH-N-H bond angle in NH4> H-N-H bond angle in N₂H₂
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- Ketene, C2H2O, is a reactant for synthesizing cellulose acetate, which is used to make films, fibers, and fashionable clothing. (a) Write the Lewis structure of ketene. Ketene does not contain an OH bond. (b) Identify the electron-region geometry and the molecular geometry around each carbon atom and all the bond angles in the molecule. (c) Identify the hybridization of each carbon and oxygen atom. (d) Is the molecule polar or nonpolar? Use appropriate data to support your answer.Formamide, HC(O)NH2, is prepared at high pressures from carbon monoxide and ammonia, and serves as an industrial solvent (the parentheses around the O indicate that it is bonded only to the carbon atom and that the carbon atom is also bonded to the H and the N atoms). Two resonance forms (one with formal charges) can be written for formamide. Write both resonance structures, and predict the bond angles about the carbon and nitrogen atoms for each resonance form. Are they the same? Describe how the experimental determination of the HNH bond angle could be used to indicate which resonance form is more important.For each of the following molecules, complete the Lewis structure and use the VSEPR model to determine the bond angles around each central atom. Note that the drawings are only skeleton structures and may depict the angles incorrectly.
- Consider the following compounds: CO2, SO2, KrF2, SO3, NF3, IF3, CF4, SF4, XeF4, PF5, TF5, and SCl6. These 12 compounds are all examples of different molecular structures. Draw the Lewis structures for each and predict the molecular structures. Predict the bond angles and the polarity of each. (A polar molecule has a net dipole moment, while a nonpolar molecule does not.) See Exercises 25 and 26 for the molecular structures based on the trigonal bipyramid and the octahedral geometries.Formula Lewis Electron Molecular Bond Polar or Attractive Structure Pair Geometry Angle Force Non Polar Geometry Between Molecules CH4 Around First C Around First C C2H4 Around First C Around First C C,H2 Around First C Around First C CH;OH Around O Around O C2H;OH Around O Around O CH20 CH,OCH, Around O Around O CH;COOH Central C Central C НСООН Central C Central C CH;NH2 Around N Around N CH;COCH; Central C Central CRank the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest boiling point, choose 2 next to the substance with the next highest boiling point, and so on. substance A B с D : 0: chemical symbol, chemical formula or Lewis structure H-O- - H 1 C H CO - 0 | C | H H Al₂O3 0₂ — :O: -0 - - H boiling point ✓ (Choose one) 1 (highest) 2 3 4 (lowest) (Choose one) (Choose one) (Choose one)
- 0=c=0; Lewis electron-dot diagrams for CO2 and SO2 are given above. The molecular geometry and polarity of the two substances are the same because the molecular formulas are similar the same because C and S have similar electronegativity values different because the lone pair of electrons on the S atom make it the negative end of a dipole D different because S has a greater number of electron domains (regions of electron density) surrounding it than C hasFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name acetic acid dimethyl ether compound hypobromous acid formula or Lewis structure H :0: H-C-C-O-H H H H-C-0-C H H H T HBrO | H Between molecules of the compound? yes O O no O yes no yes hydrogen-bonding force no Between molecules of the compound and molecules of water? O O yes no yes no yes no XWhat is the molecular geometry about the central atom in the angle shown in the molecule below? O HIN: H—N—C—C- H—C—H O trigonal planar O tetrahedral O trigonal pyramid O square planar O bent :O: -H
- Chemistry Identify the electron pair geometry (epg), molecular geometry (mg), and bond angle for the atom C. B A OH NH lo epg: tetrahedral; mg: Tinear; 180° epg: tetrahedral; mg: bent; <109° Oepg: linear; mg: linear; 180° Oepg: tetrahedral; mg: trigonal pyramid; 109 epg: trigonal planar; mg: bent; 120° epg: tetrahedral; mg: bent; 109°Rank the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest boiling point, choose 2 next to the substance with the next highest boiling point, and so on. substance A B C H H - - chemical symbol, chemical formula or Lewis structure H :0: | || C 1 H | H H | || C-N- | H H - F₂ :NEN 0: :0: - H | C C-O- — H | C I H - H — - H - boiling point (Choose one) ✪ (Choose one) ✪ (Choose one) (Choose one) 09:39 6 00 AThe Lewis structures of methane, the carbonate ion, carbon dioxide, and the sulfite ion are given. Methane, CH4 Carbonate ion, CO²- Carbon dioxide, CO₂ Sulfite ion, SO3- H H-3-H -I :0= C Predict the molecular shape of methane. bent linear tetrahedral O trigonal planar (120°) O trigonal pyramidal 0: Predict the molecular shape of carbon dioxide. 0=c=0 Predict the molecular shape of the carbonate ion. bent :0: tetrahedral linear trigonal planar (120°) trigonal pyramidal Predict the molecular shape of the sulfite ion.