What are the molar concentrations of acetic acid (CH,COOH) and sodium acetate (CH,COONA) in an aqueous solution buffered at a pH of 4.03 that has a freezing point of -2.68 °C? Assume complete dissociation of sodium acetate and a density of 1.02 g/mL for the solution. The pKa for CH,COOH is 4.75. [CH,COOH] : M [CH;COONA] M * TOOLS х10'

What are the molar concentrations of acetic acid (CH,COOH) and sodium acetate (CH,COONA) in an aqueous solution buffered at a pH of 4.03 that has a freezing point of -2.68 °C? Assume complete dissociation of sodium acetate and a density of 1.02 g/mL for the solution. The pKa for CH,COOH is 4.75. [CH,COOH] : M [CH;COONA] M * TOOLS х10'

Chemistry

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Chapter15: Acid-base Equilibria

Section: Chapter Questions

Problem 7ALQ: You have a solution of the weak acid HA and add some HCl to it. What are the major species in the...

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A quantity of 0.25 M sodium hydroxide is added to a solution containing 0.15 mol of acetic acid. The final volume of the solution is 375 mL and the pH of this solution is 4.45. a What is the molar concentration of the sodium acetate? b How many milliliters of sodium hydroxide were added to the original solution? c What was the original concentration of the acetic acid?
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?
Calculate the pH of a solution prepared by mixing 49.0 mL of butyric acid, HC4H7O2, with 6.15 g of KOH in water. The following data about butyric acid may be helpful: density=0.9595g/mL;K a =1.54105
8-71 Explain why you do not need to know the chemical formula of a buffer compound to use it.
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.
Blood contains several acid base systems that tend to keep its pH constant at about 7.4. One of the most important buffer systems involves carbonic acid and hydrogen carbonate ion. What must be the ratio of [HCO3] to [H2CO3] in the blood if the pH is 7.40?
Metacresol purple is an indicator that changes from yellow to purple at pH 8.2. (a) What is Ka for this indicator? (b) What is its pH range? (c) What is the color of a solution with pH 9.0 and a few drops of metacresol purple?
A friend asks the following: Consider a buffered solution made up of the weak acid HA and its salt NaA. If a strong base like NaOH is added, the HA reacts with the OH to form A. Thus the amount of acid (HA) is decreased, and the amount of base (A) is increased. Analogously, adding HCI to the buffered solution forms more of the acid (HA) by reacting with the base (A). Thus how can we claim that a buffered solution resists changes in the pH of the solution? How would you explain buffering to this friend?
What is the pH of the solution obtained by titrating 1.30 g of sodium hydrogen sulfate, NaHSO4, dissolved in 50.0 mL of water with 0.175 M sodium hydroxide until the equivalence point is reached? Assume that any volume change due to adding the sodium hydrogen sulfate or to mixing the solutions is negligible.
You have a solution of the weak acid HA and add some HCl to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Malic acid is a weak diprotic organic acid with Ka1 = 4.0 104 and Ka2 = 9.0 105. a Letting the symbol H2A represent malic acid, write the chemical equations that represent Ka1 and Ka2. Write the chemical equation that represents Ka1 Ka2. b Qualitatively describe the relative concentrations of H2A, HA, A2, and H3O+ in a solution that is about one molar in malic acid. c Calculate the pH of a 0.0175 M malic acid solution and the equilibrium concentration of [H2A]. d What is the A2 concentrationin in solutions b and c?

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