Using your model kits, make trans-1-tert-butyl-4-methylcyclohexane. Draw the least stable and most stable chair conformation. The structures must be related as chair inversions. Least stable Chair Conformation Most stable Chair Conformation 58

Using your model kits, make trans-1-tert-butyl-4-methylcyclohexane. Draw the least stable and most stable chair conformation. The structures must be related as chair inversions. Least stable Chair Conformation Most stable Chair Conformation 58

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter4: Organic Compounds: Cycloalkanes And Their Stereochemistry

Section4.SE: Something Extra

Problem 55AP: myo-Inositol, one of the isomers of 1,2,3,4,5,6-hexahydroxycyclohexane, acts as a growth factor in...

See similar textbooks

Related questions

Q: hat is the most stable chair conformation form of trans 1 -tert-butyl -3-methylcyclohexane? a)Axial…

Q: 17) In the lowest energy conformation of the compound shown below, how many alkyl substituents are…

A: In order to answer this question, we have to first draw the chair conformation of the given…

Q: 1. construct an energy diagram to show the variation in the free energy of the molecule as the front…

Q: Sight along the C2-Cl bond of 2-methylpropane (isobutane). a. Draw a Newman projection of the most…

A: “Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

Q: On a cyclohexane ring, an axial carboxyl group has a conformational energy of 5.9 kJ (1.4 kcal)/mol…

A: Given: On a cyclohexane ring, an axial carboxyl group has a conformational energy of 5.9kJ relative…

Q: Consider 1-bromopropane, CH3CH2CH2Br. (a) Draw a Newman projection for the conformation in which …

A: (a)

Q: Which of the following molecules represents the lowest energy conformation of…

Q: CH aswers: kJ/mol. a. The energy difference is b. In the more stable chair: V position. • The…

A: Here you go for the following steps i hope It would help you

Q: D-Pinitol is an interesting hexahydroxy cyclohexane, whose structure is shown below. HO OH HO/4 HO…

Q: Arrange the compounds in order of increasing solubility in water (least first). CH3 CH || CH;CH, CH…

A: Solubility of aldehyde and ketones depends upon number of carbon atoms.

Q: 10. Rank the indicated conformations in order of decreasing stability (from L-R). CH₂ CH3 H CH, Н…

Q: BASED ON THE FIGURE WHAT IS 1. The least stable conformation of 1-bromo-3-ethylcyclohexane. 2. The…

A: More the number of substituents placed in equitorial Position, that conformation is most stable.…

Q: Question attached

A: The given compound can also be written as :

Q: of -1? CH3 CH3 :F: .. H3C-C-CH3 H-N-CH3 :F-B-F : CH3 :F: H3c.CH3 H (a) (b) (c) (d) (e) HI

Q: 5. Given the molecule 1,2-dimethyl-4-bromocyclohexane below: CH3 Br" CH3 NOTE: All groups are cis…

A: see below

Q: 17) In the lowest energy conformation of the compound shown below, how many alkyl substituents are…

Q: Consider 2-methylbutane (isopentane). Looking along the C2-C3 bond: a) Draw a Newmann projection of…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: 1) Use conformations A and B shown below to answer the following questions. Br. H Br H H H H H H CI…

Q: 4. What is the relationship (resonance structures, constitutional isomers, conformational isomers,…

Q: Which of the following conformations of 1,2-dibromocyclohexane is the LEAST stable? Select one: Br H…

A: 1st:- both bromines are trans at 180 degree so there are no any interaction with lone pair-lone…

Q: Using your model kits, make cis-1-tert-butyl-3-methylcyclohexane. Draw the least stable and most…

A: Most stable chair: First you have to put bulky group (t-Bu) in equatiorial position for…

Q: 5. Select the most stable conformer of cis-1, 3- cyclohexane diol. HO OH OH OH НО. OH Брон OH OH B D…

Q: 8. Which of the following is the most stable conformation of trans-1-tert-butyl-3-…

A: Given compound: trans-1-tert-butyl-3-methylcyclohexane

Q: 3. (20) Cyclohexane may go through ring-flipping as shown below. 5 (a) Draw both of the possible…

Q: Part A Of all the possible cyclooctanes that have one chloro substituent and one methyl substituen…

Q: Write the structure for the most stable conformer of trans-1-iodo-3-ethylcyclohexane. Calculate the…

Q: 28. What is the boiling point ranking for the molecules below? (A) CH3CH2CH2 CH2CHO; (B)…

Q: 1. The cyclohexane derivative shown below exists primarily in its most stable chair conformation.…

A: The most stable chair conformation of any substituted cyclohexane is the one in which bulkier…

Q: CH2=CHCI is more reactive than CH2=CH-CH2CI. (A) True B False

Q: Draw the most stable conformers of trans-1-Bromo-4-methylcyclohexane and…

Q: Conformational studies on ethane-1,2-diol (HOCH2¬CH2OH) have shown the most stable conformation…

A: Gauche conformation of ethane-1,2-diol is the most stable conformation when compared to…

Q: 48. Which of the following chair conformations represents trans-1,3-dimethylcyclohexane? IV A) I B)…

A: In the chair conformation, cis and trans configurations are determined on the basis of the…

Q: Choose the structure for cis-1-bromo-3-methylcyclohexane in its most stable conformation. CH3 CH3 Br…

A: In Cis 1-bromo-3-methycyclohexane when both substituted group are axial then less stable because of…

Q: can this be explained please with full and understandable explanation

Q: 40. Beginning with the Newman projection below as number 1, draw each of the six conformations for…

A: The six confirmations for the molecule are as follows: Among the following structures, staggered…

Q: How to draw the more stable chair conformer of cis-1-ethyl-2-methylcyclohexane? Thank you

A: The planar structure of cis-1-ethyl-2-methylcyclohexane can be drawn as-…

Q: For the compound below please identify the position of equilibrium (which chair conformation is more…

A: I have given the answer in the explanation section. Hope you will understand that.

Q: Represent in perspective the most stable conformer of trans-4 isopropylcyclohexan-1-ol.

A: When Trans 1,4 disubstituent's come into scene. Its always axial-axial or equatorial-equatorial. If…

Q: Using your model kits, make trans-1-tert-butyl-3-methylcyclohexane. Draw the least stable and most…

A: tert-butyl group on axial position form less stable conformation due to more 1,3 diaxial interaction

Q: 1. Arrange each set in order of decreasing priority using (Cahn-Ingold-Prelog) priority rules…

Q: 20. Which of the following is a gauche conformation for butane? CH3 H, H CH3 CH3 CH3 H3C CH3 H, H YH…

Q: 4. Perform a conformational analysis on cyclohexane derivative I. Draw out both possible conformers…

A: The explanation is given below-

Q: Rank the following groups in order of decreasing priority. a.−COOH, −H, −NH2, −OH b.−H, −CH3, −Cl,…

A: The following groups are to be ranked in order of decreasing priority: – COOH, – H, – NH2, – OH –…

Q: (c) Rank the compounds in each group in order of decreasing ^max : (i) -CH=CH- CH=CH2 CH3 (ii) CH3…

Q: 4. Draw the most stable conformation of: a) trans-1,4-diisopropylcyclohexane. io b)…

A: since you have posted multiple questions. we are entitiled to answer only first question with first…

Q: 4. Br Br Br -CI Br - CI H3C H3C H3C CH3 C Which of these is a Fischer projection of (S)…

A: (S)1-bromo-1-chloro-1-fluoropropane

Q: Br A. A B. B Select the most stable conformation of 3-bromo-2-methylpentane, viewed through the…

A: ->the conformer in which bulkier group are opposite to each other are most stable.

Q: Which conformer of pentane is the least stable? CH CH2CH3 CH,CH, CH3 CH2CH3 H. HCH,CH3 H. H. CH H'…

A: In the Newman projection , when the bulky substituents are Anit staggered to each other , this is…

Q: 5. Given the molecule 1,2-dimethyl-4-bromocyclohexane below: CH3 20 Br "CH 3 NOTE: All groups are…

Question

Using your model kits, make trans-1-tert-butyl-4-methylcyclohexane. Draw the least stable and most
stable chair conformation. The structures must be related as chair inversions.
Least stable Chair Conformation
Most stable Chair Conformation
58

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Similar questions

myo-Inositol, one of the isomers of 1,2,3,4,5,6-hexahydroxycyclohexane, acts as a growth factor in both animals and microorganisms. Draw the most stable chair conformation of myo-inositol.
Gibbs free energy differences between axial-substituted and equatorial-substituted chair conformations of cyclohexane were given in Table 2.4. (a) Calculate the ratio of equatorial to axial tert-butylcyclohexane at 25C. (b) Explain why the conformational equilibria for methyl, ethyl, and isopropyl substituents are comparable but the conformational equilibrium for tert-butylcyclohexane lies considerably farther toward the equatorial conformation.
Using your model kits, make cis-1-tert-butyl-3-methylcyclohexane. Draw the least stable and most stable chair conformation. The structures must be related as chair inversions. Least stable Chair Conformation Most stable Chair Conformation
Draw alternative chair conformations for the following substituted cyclohexane and determine which chair is more stable. C HO H ОН In its most stable chair conformation, indicate the orientation of each of the labeled groups in this substituted cyclohexane. Group a: Group b: Group c:
CYCLOHEXANE 2D REPRESENTATION Cyclohexane Chair by stereoaisier H H H. „CH2. H CH H. H H V STAGGERED O ECLIPSED O 1,3-DIAXIAL INTERACTION CHAIR BOAT CHAIR In which conformation are the hydrogen atoms farthest apart? Which is the preferred conformation? Give reasons for your answer. Which is the eclipsed conformation?
Compare the following conformers of 1-fluoropropan-1-ol. Match each conformer to their corresponding relative energy. Recall, the more stable the conformer the lower the energy. OH CH3 'F 2. HOH 2nd Highest Energy H 2nd Lowest Energy H3C 3. H. ОН Lowest Energy H 'F Highest Energy ČH3 4. H3C, OH 'F 1. >
Using your model kits, make trans-1-tert-butyl-3-methylcyclohexane. Draw the least stable and most stable chair conformation. The structures must be related as chair inversions. Least stable Chair Conformation Most stable Chair Conformation Sl bom on chira
Draw the structure for the most stable chair conformation of trans-1-tert-butyl-3-chlorocyclohexane. Use the cyclohexane conformation drawing tool and guide points to draw each structure. C1 M C™ X Ĉ
Order the conformations of butane from lowest energy to highest energy (1 being the lowest energy). CH₂ H. H A B C D H A CH₂ H H₂ H CH3 CH₂ B H 'H H₂C CH₂ H H 4 1 3 2 -H 'H H H CH₂ H D -CH₂ H
5. Select the most stable conformer of cis-1, 3- cyclohexane diol. HO OH OH OH НО. OH Брон OH OH B D A) A B) B C) C D) DE) E OH
Indicate the position, axial or equatorial, of each of the groups shown when the ring is in its more stable chair conformation H. C OH CH(CH3)2 b a. b. C.
Draw the structure for the most stable chair conformation of cis-1-isopropyl-3-methylcyclohexane. Use the cyclohexane conformation drawing tool and guide points to draw each structure. Click and drag to start drawing a structure. E C C X E Smy ct C с 002 18 Ar