Under what circumstance is the curve for an oxidation/reduction titration asymmetric about the equivalence point?

Chemistry for Today: General, Organic, and Biochemistry
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Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
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Chapter9: Acids, Bases, And Salts
Section: Chapter Questions
Problem 9.157E: When titrating 50mL of 0.2MHCl, what quantity of 0.5M NaOH is needed to bring the solution to the...
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1.     Under what circumstance is the curve for an oxidation/reduction titration asymmetric about the equivalence point?
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