The un-ionized form of the weak acid HA does not absorb in the visible region. When it ionizes, its conjugate base (A-) absorbs light strongly at 510 nm. The following data were obtained by measuring the absorbance at 510 nm of solutions with a concen- tration of 1.0 x 10 M HA in different pH buffers. pH Absorbance 2.0 0.00 3.0 0.00 4.0 0.00 5.0 0.025 6.0 0.180 7.0 0.480 8.0 0.570 9.0 0.595 10.0 0.595 11.0 0.595 12.0 0.595

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.35AP: The sec-butyl cation can react as both a Brnsted-Lowry acid (a proton donor) and a Lewis acid (an...
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The un-ionized form of the weak acid HA does not absorb in the
visible region. When it ionizes, its conjugate base (A-) absorbs
light strongly at 510 nm. The following data were obtained by
measuring the absorbance at 510 nm of solutions with a concen-
tration of 1.0 x 104 M HA in different pH buffers.
pH
Absorbance
2.0
0.00
3.0
0.00
4.0
0.00
5.0
0.025
6.0
0.180
7.0
0.480
8.0
0.570
9.0
0.595
10.0
0.595
11.0
0.595
12.0
0.595
What is the approximate pK of HA?
Transcribed Image Text:The un-ionized form of the weak acid HA does not absorb in the visible region. When it ionizes, its conjugate base (A-) absorbs light strongly at 510 nm. The following data were obtained by measuring the absorbance at 510 nm of solutions with a concen- tration of 1.0 x 104 M HA in different pH buffers. pH Absorbance 2.0 0.00 3.0 0.00 4.0 0.00 5.0 0.025 6.0 0.180 7.0 0.480 8.0 0.570 9.0 0.595 10.0 0.595 11.0 0.595 12.0 0.595 What is the approximate pK of HA?
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