Required information During the isothermal heat addition process of a Carnot cycle, 700 kJ of heat is added to the working fluid from a source at 400°C. Determine the entropy change of the source. The entropy change of the source is KJ/K.
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- A monoatomic ideal gas (n moles) goes through a cyclic process shown below. Find the change in entropy of the gas in each step and the total entropy change over the entire cycle.A large electrical power station generates 1000 MW of electricity with an efficiency of 35.0%. (a) Calculate the heat transfer to the power station, Qh, in one day. (b) How much heat transfer Qc occurs to the environment in one day? (c) If the heat transfer in the cooling towers is from 35.0C water into the local air mass, which increases in temperature from 18.0C to 20.0C, what is the total increase in entropy due to this heat transfer? (d) How much energy becomes unavailable to do work because of this increase in entropy, assuming an 18.0C lowest temperature? (Part of Qccould be utilized to operate heat engines or far simply heating the surroundings, but it rarely is.)A 65-g ice cube is initially at 0.0C. (a) Find the change in entropy of the cube after it melts completely at 0.0C. (b) What is the change in entropy of the environment in this process? Hint: The latent heat of fusion for water is 3.33 105 J/kg.
- An ideal gas at temperature T is stored in the left half of an insulating container of volume V using a partition of negligible volume (see below). What is the entropy change per mole of the gas in each of the following cases? (a) The partition is suddenly removed and the gas quickly fills the entire container. (b) A tiny hole is punctured in the partition and after a long period, the gas reaches an equilibrium state such that there is no net flow through the hole. (c) The partition is moved very slowly and adiabatically all the way to the light wall so that the gas finally fills the entire container.Suppose you build a two-engine device with the exhaust energy output from one heat engine supplying the input energy for a second heat engine. We say that the two engines arc running in series. Let e1 and e2 represent the efficiencies of the two engines. (a) The overall efficiency of the two-engine device is defined as the total work output divided by the energy put into the first engine by heat. Show that the overall efficiency e is given by e=e1+e2e1e2 What If? For parts (b) through (e) that follow, assume the two engines are Carnot engines. Engine 1 operates between temperatures Th and Ti. The gas in engine 2 varies in temperature between Ti and Tc. In terms of the temperatures, (b) what is the efficiency of the combination engine? (c) Does an improvement in net efficiency result from the use of two engines instead of one? (d) What value of the intermediate temperature Ti results in equal work being done by each of the two engines in series? (e) What value of Ti results in each of the two engines in series having the same efficiency?(a) What is the change in entropy if you start with 100 coins in the 45 heads and 55 tails macrostate, toss them, and get 51 heads and 49 tails? (b) What if you get 75 heads and 25 tails? (c) How much more likely is 51 heads and 49 tails than 75 heads and 25 tails? (d) Dues either outcome violate the second law of thermodynamics?
- Explain how water’s entropy can decrease when it freezes without violating the second law of thermodynamics. Specifically, explain what happens to the entropy of its surroundings.A sealed container holding 0.500 kg of liquid nitrogen at its boiling point of 77.3 K is placed in a large room at 21.0C. Energy is transferred from the room to the nitrogen as the liquid nitrogen boils into a gas and then warms to the rooms temperature. (a) Assuming the rooms temperature remains essentially unchanged at 21.0C, calculate the energy transferred from the room to the nitrogen. (b) Estimate the change in entropy of the room. Liquid nitrogen has a latent heat of vaporization of 2.01 105 J/kg. The specific heat of N2 gas at constant pressure is CN2 = 1.04 103J/kg K.Prepare a table like Table 12.3 for the following occurrence: You toss four coins into the air simultaneously and record all the possible results of the toss in terms of the numbers of heads and tails that can result. (For example, HHTH and HTHH are two possible ways in which three heads and one tail can be achieved.) (a) On the basis of your table, what is the most probable result of a toss? In terms of entropy, (b) what is the most ordered state, and (c) what is the most disordered?
- Objects A and B with TA TB are placed in thermal contact and come to equilibrium. (a) For which object does the entropy increase? (b) For which object does the entropy decrease? (c) Which object has the greater magnitude of entropy change?(a) What is the change in entropy if you start with 10 coins in the 5 heads and 5 tails macrostate, toss them, and get 2 heads and 8 tails? (b) How much more likely is 5 heads and 5 tails than 2 heads and 8 tails? (Take the ratio of the number of microstates to find out.) (c) If you were betting on 2 heads and 8 tails would you accept odds of 252 to 45? Explain Why or why not. Table 15.5 10Coin Toss MacrostateNumber of Microstates (W) Heads Tails 10 0 1 9 1 10 8 2 45 7 3 120 6 4 210 5 5 252 4 6 210 3 7 120 2 8 45 1 9 10 0 10 1 Total: 1024An ideal gas is taken from an initial temperature Ti to a higher final temperature Tf along two different reversible paths. Path A is at constant pressure, and path B is at constant volume. What is the relation between the entropy changes of the gas for these paths? (a) SA SB (b) SA = SB (c) SA SB