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- How much heat is required to raise the temperature of 100. grams of water from 25C near room temperature to 100.C its boiling point? The specific heat of water is approximately 4.2Jperg-K. a.3.2104J b.32J c.4.2104J d.76JExplain the economic importance of conversions between different forms of energy and the inevitability of losses in this process.A book is held 6 feet above the floor and then dropped. Which statement is true? a.The potential energy of the book is converted to kinetic energy. b.The potential energy of the book is destroyed. c.Kinetic energy is created. d.The total energy of the system will not be conserved.
- A _________ is a device used to determine the heat associated with a chemical reaction.A rebreathing gas mask contains potassium superoxide, KO2, which reacts with moisture in the breath to give oxygen. 4KO2(s)+2H2O(l)4KOH(s)+3O2(g) Estimate the grams of potassium superoxide required to supply a persons oxygen needs for one hour. Assume a person requires 1.00 102 kcal of energy for this time period. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 1.00 102 kcal of heat, calculate the amount of oxygen consumed and hence the amount of KO2 required. The ff0 for glucose(s) is 1273 kJ/mol.Insoluble AgCl(s) precipitates when solutions of AgNO3(aq) and NaCl(aq) are mixed. AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) rH = ? To measure the energy evolved in this reaction, 250. mL of 0.16 M AgNO3(aq) and 125 mL of 0.32 M NaCl(aq) are mixed in a coffee-cup calorimeter. The temperature of the mixture rises from 21.15 C to 22.90 C. Calculate the enthalpy change for the precipitation of AgCl(s), in kJ/mol. (Assume the density of the solution is 1.0 g/mL and its specific heat capacity is 4.2 J/g K.)
- How many joules of heat are lost by 3580 kg of granite asit cools from 41.2°C to -12.9°C? The specific heat ofgranite is 0.803J/(gC) .During a recent winter month in Sheboygan, Wisconsin, it was necessary to obtain 3500 kWh of heat provided by a natural gas furnace with 89% efficiency to keep a small house warm (the efficiency of a gas furnace is the percent of the heat produced by combustion that is transferred into the house). (a) Assume that natural gas is pure methane and determine the volume of natural gas in cubic feet that was required to heat the house. The average temperature of the natural gas was 56 F; at this temperature and a pressure of 1 atm, natural gas has a density of 0.68 1 g/L. (b) How many gallons of LPG (liquefied petroleum gas) would be required to replace the natural gas used? Assume the LPG is liquid propane [ C3H8 : density, 0.5318 g/mL; enthalpy of combustion, 2219 Id/mo for the formation of CO2(g) and H2O(l) ] and the furnace used to burn the LPG has the same efficiency as the gas furnace. (c) What mass of carbon dioxide is produced by combustion of the methane used to heat the house? (d) What mass of water is produced by combustion of the methane used to heat the house? (e) What volume of air is required to provide the oxygen for the combustion of the methane used to heat the house? Air contains 23% oxygen by mass. The average density of air during the month was 1.22 g/L. (f) How many kilowatt—hours ( 1kWh=3.6106 J) of electricity would be required to provide the heat necessary to heat the house? Note electricity is 100% efficient in producing heat inside a house. (g) Although electricity is 100% efficient in producing heat inside a house, production and distribution of electricity is not 100% efficient. The efficiency of production and distribution of electricity produced in a coal-fired power plant is about 40%. A certain type of coal provides 2.26 kWh per pound upon combustion. What mass of this coal in kilograms will be required to produce the electrical energy necessary to heat the house if the efficiency of generation and distribution is 40%?If 14.5 kJ of heat were added to 485 g of liquid water, how much would its temperature increase?
- Bicycling Describe the energy conversions that occur when a bicyclist coasts down a long grade, then struggles to ascend a steep grade.A piece of iron was heated to 95.4C and dropped into a constant-pressure calorimeter containing 284 g of water at 32.2C. The final temperature of the water and iron was 51.9C. Assuming that the calorimeter itself absorbs a negligible amount of heat, what was the mass (in grams) of the piece of iron? The specific heat of iron is 0.449 J/(gC), and the specific heat of water is 4.18 J/(gC).Enthalpy a A 100.-g sample of water is placed in an insulated container and allowed to come to room temperature at 21C. To heat the water sample to 41C, how much heat must you add to it? b Consider the hypothetical reaction,2X(aq)+Y(l)X2Y(aq)being run in an insulated container that contains 100. g of solution. If the temperature of the solution changes from 21C to 31C, how much heat does the chemical reaction produce? How does this answer compare with that in part a? (You can assume that this solution is so dilute that it has the same heat capacity as pure water.) c If you wanted the temperature of 100. g of this solution to increase from 21C to 51C, how much heat would you have to add to it? (Try to answer this question without using a formula.) d If you had added 0.02 mol of X and 0.01 mol of Y to form the solution in part b, how many moles of X and Y would you need to bring about the temperature change described in part c. e Judging on the basis of your answers so far, what is the enthalpy of the reaction 2X(aq) + Y(l) X2Y(aq)?