In the radical addition of HBr to alkenes, we saw benzoyl peroxide as a radical initiator. The reaction below uses a different radical initiator: HBr NC N=N CN (radical initiator) The reaction showing the formation of the initial radicals using this initiator is shown below: CN NC NEN 2 x NC a) Show a detailed mechanism for the reaction to produce nitrogen gas and the two carbon radicals shown above. b) Show how the carbon radical produced above could react with HBr to make a bromine radical, completing the initiation step for the reaction at the top of the page. c) Show a detailed mechanism for the propagation step of the reaction at the top of the page and circle the major organic product produced from the reaction.
In the radical addition of HBr to alkenes, we saw benzoyl peroxide as a radical initiator. The reaction below uses a different radical initiator: HBr NC N=N CN (radical initiator) The reaction showing the formation of the initial radicals using this initiator is shown below: CN NC NEN 2 x NC a) Show a detailed mechanism for the reaction to produce nitrogen gas and the two carbon radicals shown above. b) Show how the carbon radical produced above could react with HBr to make a bromine radical, completing the initiation step for the reaction at the top of the page. c) Show a detailed mechanism for the propagation step of the reaction at the top of the page and circle the major organic product produced from the reaction.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.22P: Following is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h...
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a) Show a detailed mechanism for the reaction to produce nitrogen gas and the two carbon radicals shown above.
b) Show how the carbon radical produced above could react with HBr to make a bromine radical, completing the initiation step for the reaction at the top of the page.
c) Show a detailed mechanism for the propagation step of the reaction at the top of the page and circle the major organic product produced from the reaction.
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