Answered: () ¹H NMR spectrum of an alcohol…

() ¹H NMR spectrum of an alcohol (CsH12O) is shown with related integral values of the each proton peaks. Propose a structure for this alcohol and assign each protons in this structure.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter20: Carboxylic Acids And Nitriles

Section20.SE: Something Extra

Problem 67AP

See similar textbooks

Related questions

Q: A factory has wastewater discharge into river. It is known ChemicalA can be hydrolyzed. Draw…

A: SolutionWe must take into account the hydrolysis behaviour of Chemicals A and B and comprehend how…

Q: 3. Provide the reagents needed for the following reactions to occur. a. b. ОН OH OH Br

A: In the first reaction is the,SNi reaction or substitution nucleophilic internal . Generally in this…

Q: or 500.0 mLmL of a buffer solution that is 0.165 M� in CH3CH2NH2CH3CH2NH2 and 0.100 M� in…

Q: 4. What is the pH of a 0.350 M solution of lithium citrate? (K, Citric Acid = 7.4 x 104)

A: IntroductionLithium citrate is a compound formed by combining lithium ions (Li+) with citrate ions.…

Q: Assuming the initial gas pressure are equal, match the gas to the appropriate cylinder in the…

A: With increasing the molar mass of gaseous compound, dispersion force among molecule increases that…

Q: A voltaic cell is constructed in which the anode is a Cr | Cr³+ half cell and the cathode is a Ni |…

A: We have to write the anode reaction, cathode reaction and net cell reaction for given reaction.…

Q: A small part of a crystal lattice is sketched below. The unit cell is outlined in red. How many…

A: Answer:-This question is answered by using the simple concept of calculation of number of atoms in…

Q: Which one of the following reactions would produce-t-butyl-methyl ether-in-high-yield?¶ ¶ A. →…

A: Ethers are formed by the reaction between an alkyl halide and sodium alkoxide. This reaction is…

Q: is shown below: E (kJ) C₂H5CI Which of the following are true? Choose all that apply. 275 C2H4 + HCI…

A: The reaction in which energy is absorbed is endothermic reaction while reaction in which energy is…

Q: Microwave ovens use microwave radiation to heat food. The microwaves are absorbed by the water…

A: The wavelength of a radiation is 11.2 cm. Convert this wavelength into meters.

Q: Write the balanced chemical equation for the neutralization reaction between nitric acid (HNO,) and…

Q: How is Na2S2O8 an empirical formula? Can’t that compound be simplified more?

A: 1.Empirical formula represent simple whole number ratio of different element in compound. 2. Na2…

Q: Find the pOH of 25.0ml of 0.010M HCl.

A: It is based on the concept of acid and baseHere we were are required to find the pH of 0.01M of…

Q: What is wrong with the Lewis structure of OF2 as show here: F -0 = F O The Lewis structure includes…

A: The correct answer is option BThe lewis structure includes too few valence electrons

Q: Pls help ASAP. Pls i humbly request to help on both questions.

A: For first question - Oxidation number can be calculated by subtracting the oxidation number of…

Q: Which of the following amines will not show intermolecular hydrogen bonding? a) CH3NH2 b)…

A: For hydrogen bonding there must be hydrogen atom connected with electronegative atom so that the…

Q: 16- Aluminum Al in a 3.533 g soil sample was determined by precipitating as Al₂O₁ (102.0 g/mol).…

A: Mass of sample = 3.533 gMass of Al2O3 precipitate = 0.0435 gMolar mass of Al2O3 = 102 g/molfind the…

Q: The electron configurations for four main group elements are given. Match the electron configuration…

A: The Lewis dot structure represent the valence electrons of an atom and electronic configuration…

Q: Predict if the following reaction is spontaneous: 2Cr(s)+3Cl2g→2Cr3+(aq) + 6Cl-(aq)

A: Determining the spontaneity of a reaction involves analyzing the standard Gibbs free energy change…

Q: What is the major organic product? 1 & & & & & 1 2 3 4 OCH 3 5 OH (racemic) (racemic) 2 3 4 Br 5…

Q: Draw in lone pairs and write the steric number of each C, N or O. a. b. H H H H HIC- H 3 O ·C· C-N+…

A: To draw the lone pairs and write the steric number for each C,N and OSteric number is the total…

Q: A voltaic cell is constructed from a standard Al3+|Al half cell (E°red = -1.660V) and a standard…

A: It is based on the concept of electrochemistry. Here we are required to find the standard cell…

Q: Which atom(s) and/or ion(s) would have valence electrons represented by the orbital diagram? |↑↓ Po…

A: Electrons are filled in a different atomic orbital in an atom. According to the Aufbau rule, the…

Q: show the similarities and differences in the chemical reactions between alkanes and alkenes in terms…

A: a) Alkanes and alkenes both goes through combustion to give Carbon dioxide and Water.b) The two…

Q: (11) Which of the following molecules would have the following potential energy diagram for rotation…

A: First I draw energy diagram of 2,3 - dimethyl butane, then compare the given cyclohexane to…

Q: draw the reaction and the product(s) of the follwoing substitution reactions H₂C NiHy NaCH,CH,CH…

A: We’ll answer the first question since the exact one wasn’t specified. Please submit a new question…

Q: K Question 4 of 14 A skeletal structure for for bromate (BrO₂) is shown below. Starting from this…

A: Octate rule states that each atom tends to have 8 electrons in its valence shell to get the stable…

Q: CH3CHCH₂CHCH₂ CH3 CH3 OH Spell out the full name of the compound.

A: Find the longest uninterrupted chain of carbon atoms in chemistry. The parent chain, which is…

Q: Obtain the standard electrode potential and the Gibbs free energy of the reaction below: Fe(s) +…

A: We have to divide the cell reaction into two halve reactions. One is oxidation half and another is…

Q: Which compound or compounds in the following groups is (are) expected to be insoluble in water:…

A: Soluble salt : If atleast 1g of a compound can be dissolved in 100ml of water at 298 K, it is called…

Q: When 238. mg of a certain molecular compound X are dissolved in 90.0 g of benzonitrile (CHCN), the…

Q: Iron(III) oxide reacts with carbon monoxide gas to form iron and carbon dioxide. Write the balanced…

A: Introduction: In the field of chemistry, balancing equations is a crucial skill, and redox reactions…

Q: If 29.3 g of NO and 26.9 g of O₂ react together, what is the mass in grams of NO, that can be formed…

A: In the given chemical reaction nitric oxide reacts with oxygen to form nitrogen dioxide. The…

Q: Provide the IUPAC name of the organic product of the reaction between ethanoic acid and…

A: When carboxylic acids are reacted with amines they undergo condensation reactions to form amides as…

Q: The molecule below is sertraline, an antidepressant so You first met this molecule in 123.101.…

A: A Friedel-Craft reaction shows the reaction between a benzene ring and an alkyl or acyl halide in…

Q: 11 10 HSP-00-108 9 (D) 2 8 3 T 7 C8H8O2 6 ppm 5 3 4 T 3 2 T 1 0

Q: Question 2 How will you prepare the 100.00 mL each of the following standard solutions using 1.6284…

A: When a solution with a particular concentration and volume is made to dilute to another particular…

Q: shouldn't a hydride shift take place for the HI and the tH20, H+ reactions in order to get the major…

A: Alkene on treatment HI forms a secondary carbocation, which undergoes a hydride shift to form a…

Q: 2. Propose a mechanism to explain the following reaction. ОН om a + CH3 H₂SO4 Aer heat CH3 CH3

A: Alcohols in the presence of acidic condition followed by heat treatment give alkene. The reaction…

Q: The net reaction between tris and HCl can be visualized as follows: Tris + H+ = TrisH+. When 0.273 g…

Q: For the following reaction, identify the species that undergoes oxidation and the species that…

A: Oxidation is a process where a species removes one or more electrons. On the other hand, if any…

Q: 8. Classify the bonds in the following compounds as non-polar covalent, polar covalent, or ionic.…

Q: [OH-] = Determine the [OH], pH, and pOH of a solution with a [H*] of 4.8 x 10-¹2 M at 25 °C. pH = 3…

A: pH of a solution is defined as the negative logarithm of hydrogen ion concentration.Given that the…

Q: 1. Provide the major organic product for each of the following reactions. a. b. d. e. f. OH it OH OH…

A: Epoxidation of alkene takes place on reaction with peracids.CrO3, H2SO4 oxidises primary alcohol to…

Q: How much heat is required to warm 1.50 L of water from 25.0 °C to 100.0 density of 1.0 g/mL for the…

A: Volume of water = 1.50 LInitial temperature = 25.0 °CFinal temperature = 100.0 °CDensity of water =…

Q: In the titration of 50.00mL of 0.2980M HCl, 71.93mL of 0.2173M NaOH was required to reach the…

A: In this, the acid and base reaction takes place. The moles of both acid and base have to be…

Q: Consider the reaction CO(g) + 3H2(g)CH4(g) + H2O(g) Using the standard thermodynamic data in the…

Q: Atomic mass Atomic number- 12 6 16 15 How many electrons will a single atom of sulfur with no charge…

A: Given, Valence electrons are the outermost electrons which, therefore, are located on the highest…

Q: For the reaction 2BrF3 (g) → Br₂(g) + 3F₂ (g) AG = 471 kJ and AH° = 542 kJ at 264 K and 1 atm. This…

A: Recall the given reaction, Number of moles of

Q: Calculate the solubility of Pb(IO3)2 solution in which the concentration of 103 is 0.05 M. Ksp for…

A: Concentration of IO3- = 0.005MKSP == 3.2 X 10-13

Concept explainers

Mass Spectrometry

This process is an instrumental method in which a sample is changed to fast moving positive ions by electron bombardment. The charged particles vary due to their different mass to charge ratio and are estimated with the help of this difference. It is also called mass spectroscopy.

Question

(1) ¹H NMR spectrum of an alcohol (C5H12O) is shown with related integral values
of the each proton peaks. Propose a structure for this alcohol and assign each protons in this
structure.
1H
N->
2
2H
elle
8μ (ppm)
6H
3H
il
1
0

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Description of the question

VIEW

Step 2: Answer

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Propose a structural formula for the analgesic phenacetin, molecular formula C10H13NO2, based on its 1H-NMR spectrum.
Assign their proton signals and interpret the spectra (1H-NMR).
Find how many peaks will appear in the proton (1H) NMR spectrum and carbon (13C) NMR spectrum of each molecue. Don't take into account splitting in the proton(1H) NMR
A'2 The 'H-NMR spectra of cyclohexanol and cyclohexanone are given below. Identify which spectrum belongs to which compound and assign the peaks in each spectrum that substantiate your decision.
6) The NMR spectrum of this dimethyl ether is complicated, but the diphenol has a very simple NMR: there are only two types of protons on the rings (marked a and b). Explain. OMe 0 a b OH a OMe dimethyl ether Он diphenol b
C9H10O2 analyze the structure from the 1H nmr data
Indicate two basic differences that exist between the spectra of 1H y 13C in NMR.
Which of the protons in the following molecule appear at the highest 8-value in the ¹H NMR spectrum? Explain your reasoning. H₂ iii iv H CH3 i y HC
Following are the NMR spectra of three isomeric esters with the formula C7H14O2, all derived from propanoic acid. Provide a structure for each.
An unknown compound has the formula C5H10O2. Elucidate its structure by scrutinizing its 1H NMR spectra, shown. Specifically, label each different type of H atom in the final structure with its NMR chemical shift in ppm.
(a) Rank each proton shown below in terms of relative chemical shift in the ¹H NMR spectrum. (1 = most upfield, 3 = most downfield) (i) (iii) H JO [ Ⓒ
The mass spectrum of 1-ethyl-1-methylcyclohexane shows many fragments, with two in very large abundance. Kne appears af m/z=111 and the other appears at m/z=97. Identify the structure of each of these fragments.