Give the product of the reaction shown below. Would the enantiomer or a diastereomer of the molecule below yield the same product? Show the product for either case.. Ph Br NaOH Ph Δ
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- Suppose we aempt the conversion of fumaric acid to deuterated malic acid with BD3·THF,followed by oxidation with D2O2in NaOD(aq). Show all the possible stereoisomers (as Fisherprojections) that may be formed, and draw the mechanistic pathways (showing stereochemistry)that lead to these possible products4 Show how the compound thiodiazine~C21H26N2S2~decomposes anaerobically and how these end products in turn decompose aerobically to stabilized sulfur and nitrogen compounds.What is the the stereochemistry of the two chiral centres in the product O? R or S? Is the hydride delivered from the re or the si face of the ketone in N?
- Write out all the isomers of the compound with molecular formula C4H10O . Select the normal/ primaryisomer and treat it with conc. H2SO4 and heat. Identify the reaction and give the product ‘A’ from it. 2. When ‘A’ is treated with HBr in the presence of a peroxide, give the name and structure of the product.What products would ypu obtain from reaction of 2,4-dimethyl-2-pentene with BH3, followed by H2O2, OH-? Show its complete reaction mechanism.What's the mechanism for the SN2 reaction of NaI with 1-bromobutane?
- The reaction of 2-ethyl-1-pentene with Br2, with H2 + Pd/C, or with R2BH/THF followed by aqueous HO- + H2O2 leads to a racemic mixture. Explain why a racemic mixture is obtained in each case.Can you explain how to predict the major oganic products for this structure? Since there is cirality involved what is the best way to display inversion for this S2N reaction?The first step in the metabolism of glycerol, formed by digestion of fats, is phosphorylation of the pro-R—CH2OH group by reaction with adenosine triphosphate (ATP) to give the corresponding glycerol phosphate plus adenosine diphosphate (ADP). Show the stereochemistry of the product.
- Following are diastereomers (A) and (B) of 3-bromo-3,4-dimethylhexane. On treatment with sodium ethoxide in ethanol, each gives 3,4-dimethyl-3-hexene as the major product. One diastereomer gives the E alkene, and the other gives the Z alkene. Which diastereomer gives which alkene? Account for the stereoselectivity of each -elimination.please provide the machanisms of 1a, 1e, 1f4.4 Show how the compound thiodiazine - C21H26N2S2 - decomposes anaerobically and how these end products in turn decompose aerobically to stabilized sulfurand nitrogen compounds.