Explain the differences in acidity between p-cyanobenzoic acid and m-cyanobenzoic acid. Illustrate your answer appropriately, showing the acid-base reaction that takes place with each of these and explaining in such terms as electronic (inductive or resonance) and/or steric effects.

Q: b) Rank the following compounds in decreasing order of expected acidity (i.e. from strongest to…

A: The ranking with explanation is as follows:

Q: NH2 HO You have access to the following solutions for your experiment: 1 M NaOH 1 М НC 1 M CH3COOH 1…

A: first, take all the compounds in the separating funnel in ethyl acetate. Then add water and 1M…

Q: A precursor for para-aminophenol, para-nitrophenol, can be obtained by the nitration of phenol using…

A: Nitration is electrophilic aromatic substitution reaction.

Q: Suggest a reason why the nitroso group, -N=O, is ortho-para directing whereas the nitro group, -NO2,…

A: Nitroso group -N=O is an ortho-para directing whereas the nitro group -NO2 is meta directing group.

Q: Rank these nucleophiles from most to least reactive for substitution reactions and give a brief…

A: The nucleophilicity of a species depends on various factors such as negative charge density,…

Q: Outline syntheses of each of the following from aniline and any necessary organic or inorganic…

A: (a) Synthesis of p-Nitroaniline, is as follows:-

Q: Under the acidic extraction conditions with aqueous sulfuric acid, benzoic acid will be found…

A: We have an acid extraction with sulphuric acid , we have to see In what form benzoic acid will be…

Q: Write methanol and semi-acetal, acetal, semi-ketal and ketal products together with their mechanism…

A: The mechanism of semi acetal and acetal given by methanol and propanal is -

Q: Pyridine undergoes electrophilic aromatic substitution preferentially at the 3 position as…

A:

Q: 1. Arrange the following compounds in order of increasing acidity and explain the reason for the…

A: Ethanoic acid, Butanoic Acid, Benzoic Acid, Salicyclic acid all are organic acids.

Q: Why are 2-nitrobenzoic acid and 2-chlorobenzoic acid stronger acids than benzoic acid?

A:

Q: b) Place the styrene, TS-1, TS-2 and (R) styrene oxide and (S) styrene oxide on a single reaction…

A: In catalytic transition state, catalytic molecule combine with different transition state and…

Q: Which is the stronger base: N-methylaniline (C6H5NHCH3) or benzylamine (C6H5CH2NH2). Explain your…

A: The stronger base out of N-methylaniline and benzylamine has to be determined on the basis of…

Q: 5-decanol SH

A:

Q: If you have 1L of 1M Lys-Ser at its pI, how many moles of NaOH would be required to convert it to…

A: 1 L of 1 M Lys-Ser would contain 1 mol of Lys-Ser. The structure of Lys-Ser is:

Q: H OSIET3 OSIME3 МеОН H2N + Lewis acid (cat), CH3CN

A:

Q: Which compound (i or ii) is the stronger base? Discuss your answer comprehensively by amongst other…

A:

Q: Describe all the steps of the reaction related to obtaining fumaric acid starting from maleic…

A: The reaction of maleic Anhydride with H20 in presence of Basic medium (OH-) gives Fumaric acid.

Q: Explain which of the two selected compounds is more acidic and justify, both in terms of pKa and in…

A: Acidic compound is the compound that liberates hydrogen ion.

Q: Rank the compunds in the order of increasing acidity. a. Phenol, p-methylphenol,…

A: Acidity is that which can easily donate its H+ into the solution and still stable. After donating H+…

Q: Compare isoquinoline and quinoline..Explain their basicity.Which of them will be more susceptible to…

A: Isoquinoline and quinoline are heteronuclear organic compound with one aromatic phenyl group and one…

Q: p-Nitrobenzyl alcohol is more acidic than benzyl alcohol but p-Methoxybenzyl alcohol is less acidic.…

A: The answer to this question is given below:

Q: Provide a stepwise synthesis for benzyl chloride to benzoic acid (including arrow-pushing…

A: We have to provide a stepwise synthesis for benzyl chloride to benzoic acid (including arrow-pushing…

Q: A student was given from the list of the compounds below A, B and D blindly and asked to identify…

A: In this question D- are occurred in the haloform test as it is a methyl ketone (-COCH3 group).

Q: 1. Explain the the following,giving examples and illustrations to support your answer Electrophilic…

A:

Q: p-Nitrobenzyl alcohol is more acidic than benzyl alcohol but p-methoxybenzyl alcohol is less acidic.…

A: The compounds given are p-nitrobenzyl alcohol, p-methoxybenzyl alcohol and benzyl alcohol.

Q: In the preparation of  p-Nitroaniline, there are three synthetic steps in this reaction, the first…

A:

Q: Provide summarizing results for the Synthesis of P-Nitroaniline, a 100 gram of acetanilide,  1mL of…

A:

Q: what is the chemical form of Lynestrenol and what is the salts of it  and what is the specifity of…

A: It has been used to treat the menstrual disorders.  The chemical form of Lynestrenol is,…

Q: Suggest a retrosynthetic analysis and synthesis for these molecule. OH но, HO.

A: The retrosynthesis is done for any molecule by looking the several factors like electronic…

Q: Discuss the inductive and mesomeric (resonance) effects of the following compounds in order of…

A: Groups that have a tendency to withdraw electron towards themselves in a system are said to portray…

Q: The Lewis structures of both pyridine and pyrrole have an electron pair on the nitrogen atom,…

A:

Q: According to the Evan's pKa table, phenol has a pKa of 9.95. p-Nitro and m-nitrophenol have pKas of…

A:

Q: Describe all the steps of the reaction to obtain fumaric acid starting from maleic anhydride by…

A:

Q: Write detailed mechanisms showing how pyridines and sulfuric acid catalyze the formation of…

A: The detailed mechanism and role of sulfuric acid and pyridine in the formation of acetylsalicylic…

Q: Primary amines can be prepared from amides by Hoffman's reaction. Write a general equation for the…

A: Hoffman's Reaction is the organic reaction in which primary amide is converted to primary amine by…

Q: Phenols are less acidic than carboxylic acids, with values of pKa around 10. Phenols aredeprotonated…

A:

Q: Starting with benzene, toluene, or phenol as the only sources of aromatic rings, show how to…

A: The synthesis of m-Chlorobenzoic acid can be done with toluene. First reaction is of oxidation of…

Q: acidity:ethanol,ethylene glycol, acetic acid, 2,4-pentanedione,oxalic acid solid

A: Acid is substance which release hydrogen ions and base is a substance which abstract hydrogen from…

Q: aromatic benzene ring but failed to produce a fragrant yellow solution upon subjecting it to the…

A: Now when benzene undergo nitration ( NO2+) is an electrophile which gets attached to the benzene…

Q: 13. Which acid in each pair below is the stronger acid? Please explain your answer with the…

A: Among 2-dibromoacetic acid and bromoacetic acid, 2-dibromoacetic acid is more acidic. Because,…

Q: Give a clear handwritten answer..and give all possible products

A: Claisen-Schmidt condensation:  Aromatic aldehyde/ketone without alpha hydrogens are treated with…