Except for nitrogen, the elements of Group SA(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give, successively, PCI4F, PCI,F2, -.., PF (a) Given the relative sizes of F and CI, would you expect the first two F substitutions to be at axial or equatorial positions? O axial O equatorial This answer has not been graded yet. (b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.) O PCI3F2 O PCI,F3 O PCIF4 O PFs O PCI4F

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter6: Covalent Bonding
Section: Chapter Questions
Problem 4QRT
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Except for nitrogen, the elements of Group 5A(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give, successively, PCI4F, PCI3F2, ..., PF5.
(a) Given the relative sizes of F and Cl, would you expect the first two F substitutions to be at axial or equatorial positions?
О axial
O equatorial
This answer has not been graded yet.
(b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.)
O PCI3F2
O PCI2F3
O PCIF4
O PF5
O PCI4F
Transcribed Image Text:Except for nitrogen, the elements of Group 5A(15) all form pentafluorides and most form pentachlorides. The chlorine atoms of PCI5 can be replaced with fluorine atoms one at a time to give, successively, PCI4F, PCI3F2, ..., PF5. (a) Given the relative sizes of F and Cl, would you expect the first two F substitutions to be at axial or equatorial positions? О axial O equatorial This answer has not been graded yet. (b) Which of the five fluorine-containing molecules have no dipole moment? (Select all that apply.) O PCI3F2 O PCI2F3 O PCIF4 O PF5 O PCI4F
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