Draw the curved arrow notation and predict the products when one equivalent of hydroxide in DMSO at room temperature is added to 5-bromo-1-iodopentane. i DMSO + Br i i iDraw the major organic product with lone pair electrons
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- Explain why pentane-2,4-dione forms two alkylation products (A and B) when the number ofequivalents of base is increased from one to two.Explain why pentane-2,4-dione forms two different alkylation products (Aor B) when the number of equivalents of base is increased from one totwo.Provide the curved-arrow mechanism to account for the following nucleophilic addition reaction. H20 EN NaOH NH2
- By taking into account electronegativity differences, draw the products formed by heterolysis of the carbon–heteroatom bond in each molecule. Classify the organic reactive intermediate as a carbocation or a carbanion.Under acid-catalyzed conditions, epoxides can be opened by a variety of nucleophiles other than water, such as alcohols. In such a case, the nucleophile will generally attack at the more substituted position. Using this information, predict the products for each of the following reactions (a-b): ? 1) RCO-H 2) [H₂SOJ Modify the given structure to draw the major product(s). Use the single bond tool to interconvert between double and single bonds. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. CH₂ Edit Drawing ADenote how many nucleophilic centers are present in the following molecular structure (in case of polar bonds show clearly on the structure the dipoles õ+ and d-). :o: сно
- Draw a structural formula for the major organic product of the reaction shown below. & CH₂ (oran CH3CH₂O -CuLi 2 ether You do not have to consider stereochemistry. Sn [F ? ChemDoodle H3O +#16c. Provide the missing reactants, reagents, or products for the following reaction sequences below.Explain why the C=C of an enol is more nucleophilic than the C=C of an alkene, despite the fact that the electronegative oxygen atom of the enol inductively withdraws electron density from the carbon–carbon double bond.
- b) Listed below are several hypothetical nucleophilic substitution reactions. None is synthetically useful because the product indicated is not formed at an appreciable rate. In each case provide an explanation for the failure of the reaction to take place as indicated. OMe HO + OMe + OH HO + CH; OHFill in the blanks with the MAJOR organic product in the following reactions.Provide a primary organic product(s) for each reaction shown and a proper IUPAC name