Classify the following substituents according to whether they are electron donorsresonance and the inductive mechanisms.a = acceptord = donorn = no effect3.CH₂-ÖCHSCH3dimethylsulfonioSubmit Answer-C=C-N(CH3)2HHInductive effectInductive effectInductive effectResonance effectResonance effectResonance effectRetry Entire Group 9 more group attempts remainingelectron acceptors relative to hydrogen by the References)Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by theresonance and the inductive mechanisms.a = acceptord = donorn = no effect4560-CH=CH-C=N;CH₂CH₂dimethylsulfonioSubmit AnswerInductive effectInductive effect-N(CH₂)2 Inductive effectResonance effectResonance effectResonance effectRetry Entire Group 9 more group attempts remaining

Inductive effect is based on elecronagetivity:Atom/ group accepts electron through Sigma bond is…

Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d donor n = no effect 3. CH₂ -ÖCHS Inductive effect CH₂ dimethylsulfonio GCN(CH3)₂ Inductive effect Inductive effect Resonance effect Resonance effect Resonance effect

Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. a = acceptor d donor n = no effect 3. CH₂ -ÖCHS Inductive effect CH₂ dimethylsulfonio GCN(CH3)₂ Inductive effect Inductive effect Resonance effect Resonance effect Resonance effect

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter23: Carbonyl Condensation Reactions

Section23.SE: Something Extra

Problem 35MP: Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that...

See similar textbooks

Similar questions

Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. а%3 ассеptor d = donor n = no effect 1. Inductive effect Resonance effect -CH2CH2CH2ċ-OCH3 -NHCH,CH,CH,C=N: 2. Inductive effect Resonance effect :0: 3. Inductive effect Resonance effect -N(CH3)2 Submit Answer Retry Entire Group 9 more group attempts remaining
16 What is X in the following reaction? * (i) X CH,-C=C-CH, (ii) H+/Zn CH,-C-C-CH, HNO3 02 03 KMN04 None of the above
Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. а 3 ассеptor d = donor n = no effect :0: 1. Inductive effect Resonance effect ÖCH,CH,OCH, -N(CH3)2 2. Inductive effect Resonance effect ö: S-CH3 3. Inductive effect Resonance effect methanesulfonyl Submit Answer Retry Entire Group 2 more group attempts remaining Previous Next
N-Nitrosamines by themselves are not significant carcinogens. However, they are activated in the liver by a class of iron-containing enzymes (members of the cytochrome P-450 family). Activation involves the oxidation of a C-H bond next to the amine nitrogen to a C-OH group. OH ОН N=0 N=O Og 'N- H+ H N,+ cyt P-450 N-Nitroso- 2-Нydroxy-N- nitrosopiperidine An alkyl diazonium ion piperidine (a carcinogen) Show how this hydroxylation product can be transformed into an alkyl diazonium ion, an active alkylating agent and therefore a carcinogen, in the presence of an acid catalyst.
Classify the following substituents according to whether they are electron donors or electron acceptors relative to hydrogen by the resonance and the inductive mechanisms. а 3 ассеptor d = donor n = no effect :o: 1. Inductive effect Resonance effect -0-CCH,CH,ĈCH3 ÖCH3 2. Inductive effect Resonance effect -N: Inductive effect Resonance effect 3.
The following rate equation has been experimentally established for this process: Rate = = K[HOT][CH3CH₂Br] The energy diagram for this process is shown below: Free energy (G) 50 H₂C H-C-Br H Reaction coordinate CH3 HO-C-H+ H Identify the two characteristic arrow-pushing patterns that are required for this mechanism: O Br
Et Et-N: Et Me ΘΗ Me: N Me Me pK₂ = 12.5 Me Me Me: `N° N Me Me Me H Et Et (a) Add electron-flow arrows to show how the electrons move in this reaction. Et pK₂ = 10 (b) Does the equilibrium for this reaction favor the starting materials, the products, or neither?
|| A A = B = C= Complete the reaction N-R My MH₂ NA PI-NH₂ G H ₂ OH S Puflux PI-NH₂ + B
Given the dissociation constants for each deprotonation, what is the dissociation constant for the overall reaction (Ka’’)? H3PO4 + H2O H2PO4- + H3O+ Ka = 7.11 x 10-3 H2PO4- + H2O HPO42- + H3O+ Ka’ = 6.32 x 10-8 Overall: H3PO4 + 2 H2O HPO42- + 2 H3O+ Ka’’ = ?
2) Draw curved arrows to represent the flow of electrons during the following reaction :ö: CN CN но CN H. H30* H + H2O 1:Z
What is the product of this reaction? 1) MENH2 2) LİAIH4 (excess) 3) O (еxcess) pyridine 4) NaOH (1 eq) NHMe 'NMe OH `NHMe OH HO,
Which molecule has the lowest pka? H ofe O A B 00 U A B H H H Z=O Ⓒ с