Calculating the pH of a weak acid titrated with a strong base0/5IzabellaAn analytical chemist is titrating 221.8 mL of a 0.6800M solution of benzoic acid (HC H₂CO₂) with a 0.9000M solution of NaOH. The pK of benzoic acid is4.20. Calculate the pH of the acid solution after the chemist has added 135.5 mL of the NaOH solution to it.Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of NaOH solution added.Round your answer to 2 decimal places.pH = ☐☑?嘛18Ar

Ph of the solution is 3.82Explanation:To calculate the pH of the solution after adding the NaOH…

Answered: Calculating the pH of a weak acid…

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter15: Additional Aqueous Equilibria

Section: Chapter Questions

Problem 93QRT: When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence...

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When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.
Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.
Aniline hydrochloride, (C6H5NH3)Cl, is a weak acid. (Its conjugate base is the weak base aniline, C6H5NH2.) The acid can be titrated with a strong base such as NaOH. C6H5NH3+(aq)+OH(aq)C6H5NH2(aq)+H2O(l) Assume 50.0 mL of 0.100 M aniline hydrochloride is titrated with 0.185 M NaOH. (Ka for aniline hydrochloride is 2.4 105.) (a) What is the pH of the (C6H5NH3) solution before the titration begins? (b) What is the pH at the equivalence point? (c) What is the pH at the halfway point of the titration? (d) Which indicator in Figure 17.11 could be used to detect the equivalence point? (e) Calculate the pH of the solution after adding 10.0, 20.0, and 30.0 mL of base. (f) Combine the information in parts (a), (b), (c), and (e), and plot an approximate titration curve.
For the titration of 50.0 mL of 0.150 M ethylamine. C2H5NH2, with 0.100 M HCl, find the pH at each of the following points, and then use that information to sketch the titration curve and decide on an appropriate indicator. (a) At the beginning, before HCl is added (b) At the halfway point in the titration (c) When 75% of the required acid has been added (d) At the equivalence point (e) When 10.0 mL more HCl has been added than is required (f) Sketch the titration curve. (g) Suggest an appropriate indicator for this titration.
Fifty cm3 of 1.000 M nitrous acid is titrated with 0.850 M NaOH. What is the pH of the solution (a) before any NaOH is added? (b) at half-neutralization? (c) at the equivalence point? (d) when 0.10 mL less than the volume of NaOH to reach the equivalence point is added? (e) when 0.10 mL more than the volume of NaOH to reach the equivalence point is added? (f) Use your data to construct a plot similar to that shown in Figure 14.10 (pH versus volume NaOH added).
When a diprotic acid, H2A, is titrated with NaOH, the protons on the diprotic acid are generally removed one at a time, resulting in a pH curve that has the following generic shape: a. Notice that the plot has essentially two titration curves. If the first equivalence point occurs at 100.0 mL NaOH added, what volume of NaOH added corresponds to the second equivalence point? b. For the following volumes of NaOH added, list the major species present after the OH reacts completely. i. 0 mL NaOH added ii. between 0 and 100.0 mL NaOH added iii. 100.0 mL NaOH added iv. between 100.0 and 200.0 mL NaOH added v. 200.0 mL NaOH added vi. after 200.0 mL NaOH added c. If the pH at 50.0 mL NaOH added is 4.0, and the pH at 150.0 mL NaOH added is 8.0, determine the values Ka1, and Ka2 for the diprotic acid.
Morphine, C17H19O3N, is a weak base (K b =7.4107). Consider its titration with hydrochloric acid. In the titration, 50.0 mL of a 0.1500 M solution of morphine is titrated with 0.1045 M HCl. (a) Write a balanced net ionic equation for the reaction that takes place during titration. (b) What are the species present at the equivalence point? (c) What volume of hydrochloric acid is required to reach the equivalence point? (d) What is the pH of the solution before any HCl is added? (e) What is the pH of the solution halfway to the equivalence point? (f) What is the pH of the solution at the equivalence point?
Consider the nanoscale-level representations for Question 110 of the titration of the aqueous weak acid HX with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: After a very small volume of titrant has been added to the initial HX solution? When enough titrant has been added to take the solution just past the equivalence point? Halfway to the equivalence point? At the equivalence point? Nanoscale representations for Question 110.
Calculating the pH of a weak acid titrated with a strong base An analytical chemist is titrating 109.4 mL of a 0.7700M solution of hydrazoic acid (HN3) with a 0.5800M solution of NaOH. The pK of hydrazoic acid is 4.72. Calculate the pH of the acid solution after the chemist has added 163.3 mL of the NaOH solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of NaOH solution added. Round your answer to 2 decimal places. pH ☑ ? 00. 18 Ar
O ACIDS AND BASES Calculating the pH of a weak acid titrated with a strong base pH An analytical chemist is titrating 240.9 mL of a 1.000M solution of butanoic acid (HC3H,CO₂) with a 0.2500M solution of NaOH. The pK of butanoic acid is 4.82. Calculate the pH of the acid solution after the chemist has added 630.6 mL of the NaOH solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of NaOH solution added. Round your answer to 2 decimal places. = 0 X 1/5 S Sabrina
Calculating the pH of a weak base titrated with a strong acid 0/5 Izabella An analytical chemist is titrating 165.0 mL of a 0.7400M solution of methylamine (CH3NH2) with a 0.4100M solution of HNO3. The pK of methylamine is 3.36. Calculate the pH of the base solution after the chemist has added 318.6 mL of the HNO3 solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HNO 3 solution added. Round your answer to 2 decimal places. pH = ☐ ☑ ? 18 Ar
Calculating the pH of a weak base titrated with a strong acid 0/5 Izabella An analytical chemist is titrating 165.0 mL of a 0.7400M solution of methylamine (CH3NH2) with a 0.4100M solution of HNO3. The pK of methylamine is 3.36. Calculate the pH of the base solution after the chemist has added 318.6 mL of the HNO3 solution to it. Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HNO3 solution added. Round your answer to 2 decimal places. pH = ☐ ☑ ك Ar B•

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