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- Following are structural formulas for 1,4-dioxane and piperidine. 1,4-Dioxane is a widely used solvent for organic compounds. Piperidine is found in small amounts in black pepper (Piper nigrum). (a) Complete the Lewis structure of each compound by showing all unshared electron pairs. (b) Predict bond angles about each carbon, oxygen, and nitrogen atom. (c) Describe the most stable conformation of each ring and compare these conformations with the chair conformation of cyclohexane.Calculate strain energy for the conformer pictured below, using strain energy increments from the table. Strain Energy for Alkanes Interaction / Compound kJ/mol keal/mol H:H eclipsing 4.0 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CH3 eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 115 27.5 cyclobutane 110 26.3 cyclopentane 26,0 6.2 cycloheptane 26.2 6.3 cyclooctane 40,5 9.7 (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case sensitive CH H. H. H. CH3Calculate strain energy for the conformer pictured below, using strain energy increments from the table. Strain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H:H eclipsing 4.0 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CH3 eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 115 27.5 cyclobutane 110 26.3 cyclopentane 26.0 6.2 cycloheptane 26.2 6.3 cyclooctane 40.5 9.7 (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case sensitive.) CH3 H3CH,C CH3 H3C CH3 Previous Next
- Calculate strain energy for the conformer pictured below, using strain energy increments from the table. Strain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H: H eclipsing 4.0 H: CH3 eclipsing 5.8 CH3 CH3 eclipsing 11.0 gauche butane 3.8 115 110 26.0 26.2 40.5 H₂C ball & stick Strain energy = cyclopropane cyclobutane cyclopentane cycloheptane cyclooctane (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kj/mol or kcal/mol. The answer is case sensitive.) H3C H CH3 1.0 + labels 1.4 2.6 0.9 27.5 26.3 6.2 6.3 9.7Calculate strain energy for the conformer pictured below, using strain energy increments from the table. Strain Energy for Alkanes Interaction / Compound kJ/mol H: H eclipsing 4.0 H: CH3 eclipsing CH3 CH3 eclipsing gauche butane H Strain energy = cyclopropane cyclobutane cyclopentane cycloheptane cyclooctane (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case sensitive.) H CH3 ball & stick V + labels 5.8 11.0 3.8 115 H kcal/mol 110 26.0 26.2 40.5 1.0 1.4 2.6 0.9 27.5 26.3 6.2 6.3 9.7One of the chair conformations of cis-1-chloro-3-methylcyclohexane is more stable than the other by 15.5 kJ/mol. Use this, and the table below, to estimate the energy cost of a 1,3-diaxial interaction between a chlorine atom and a methyl group. 1,3-Diaxial Strain Energies for Monosubstituted Cyclohexanes kJ/mol Substituent Substituent kJ/mol -NH2 -CN, cyano 0.4 2.95 -F 0.5 -COOH 2.95 -C=CH, ethynyl 0.85 -CH=CH2 3.55 -CH3 -I 0.95 3.64 -CH2CH3 -Cl 3.65 1.1 -CH(CH3)2 1.2 4.5 -Br -C(CH3)3 10.5 -ОН 1.95 -CGH5 6.3 (Round your answer to one decimal place.) kJ/mol
- Calculate strain energy for the conformer pictured below, using strain energy increments from the table Strain Energy for Alkanes \table[[Interaction / 1 Compound,k-ol, kca-ol m H3C. J m H CH3 CH3 CH3 H[Review Topics] [References) Calculate strain energy for the conformer pictured below, using strain energy increments from the table. Strain Energy for Alkanes Interaction / Compound kJ/mol kcal/mol H: H eclipsing 4.0 1.0 H: CH3 eclipsing 5.8 1.4 CH3 : CH3 eclipsing 11.0 2.6 gauche butane 3.8 0.9 cyclopropane 115 27.5 cyclobutane 110 26.3 cyclopentane 26.0 6.2 cycloheptane 26.2 6.3 cyclooctane 40.5 9.7 (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case sensitive.) CH, CH CH3 Next Previous H3C Save and E: 15 tv MacBook Air 80 DII DD F4 F5 F6 F7 F8 F9 F10 F11 F12 $ & ) + 4. 5 7 8. %3D Y [ 11 F J + || < coConstruct the chair structures with the molecular models for trans-1-ethyl-3-methylcyclohexane. Find the energy of each conformer, the equilibrium constant Keq, and the percentage of each conformer at 25oC. Indicate which conformer is more stable.
- What is the most stable conformation for trans-1,2-dichlorocyclohexane. Describe and explain brieflya) Draw all Newman projections of your molecule's conformations in which the CH3 group and the H of the CHY2 group are positioned 'ANTI' to each other. Be sure to put in the correct X and Y atoms, bonded to the correct C atoms, for your molecule. X = FY=I Conformations = 60 deg and - 180 deg 60 deg dihedral angle = - 179.987 deg 180 deg · - dihedral angle = 179.814 deg[Review Topics] [References] Calculate Strain energy for the conformer pictured below, using strain energy increments from the table. Strain Energy for Alkanes Interaction / Compound kJ/mol H: H eclipsing H: CH3 eclipsing CH3 CH3 eclipsing gauche butane cyclopropane cyclobutane cyclopentane cycloheptane cyclooctane H₂ H (Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case sensitive.) CH3 CH3 H 4.0 5.8 11.0 3.8 115 110 26.0 26.2 40.5 H kcal/mol 1.0 1.4 2.6 0.9 27.5 26.3 6.2 6.3 9.7 Previous Next