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- The reaction of benzene with (CH);CCH;CI in the presence of anhydrous aluminum dilanide produces principally which of these? II II IV 01 ONa) Consider the reaction scheme below. -[•] PhLi HONH,, HCI A ELOH B D (i) Deduce the structures of compounds A, D and intermediate C. (ii) Outline the mechanism for the conversion of A to B.3. (a) The 3C-NMR spectrum of one of the three xylenes (dimethyl benzenes) show resonance at 8 = 10 1, 126-2, 130-0 and 138-8 ppm (proton deccupled). ident:fv the structure of the xylene and ass:gn %3D the &-values.
- (2) Draw Suve the to products specify 1)BH 3 2) HzOz, H2O, оно of the sterco chemistry 1) Hg (0AC)₂, H₂0 2) Na BH4 H+ 1 H ₂0 H₂, Rancy Ni below, making where applicable. reactions(a) Give starting materials (including molar ratios) for synthesis of compound Z. Ph E1O2C OEt F3C N. CF3Synthesize the following compound from benzonitrile (C6H5CN):? Please don't provide hand written solution....
- Use your knowledge of directing effects, along with the following data, to deduce the directions of the dipole moments in aniline and bromobenzene.Complete the following answer using the data provided here: • Molecular formula: C5H10O2 • Important IR data (cm-1): 3150-3010 (many); 1740; 1248; 1050 • All 'H NMR data (ppm, splitting, integration): 3.66 ppm (s), 3; 2.20 ppm (t), 2; 1.80 ppm (m), 2; 0.98 ppm (t), 3 Which of the following best fit this spectroscopic data? OH H. A C D E3. Predict products stereochemistry and mechanisms of the following reactions. .CO2H N. H (cat.) Ph N° A = .CO2R + A ? Ph Et solvent (i) (ii) (iii)
- GINE REASONABLE SYNTJE SËS OF THE INDICATED PeoDuCTS FROM THE GIVEN STARTING MATERIALS, Snow STERE OCHE M - ISTRY WHERE IT IS RELEVANT (*), AND SHOW ANY INTER - MEDIATES THAT COULD BE O THER REAGENTS You DEE M FIT, AS LONG A5 THHE-i MAKE CHEMICAL SENSE ARE STABLE ENOUGH TO EXIST, ISOLATED. You MAY usE ANí Ph(b) acid, HNO3 to produce compound L. The reaction of compound L with bromine, Br2 in the presence of iron tribromide, FeBr3 produced compound M. Benzene also undergoes Fridel-crafts alkylation reaction with chloroethane, CH;CH2CI using catalyst N to produce compound P. Benzene, CeHe undergoes substitution reaction with concentrated nitric Benzena, CsHe menjalani tindak balas penukargantian dengan asid nitrik, HNO, pekat untuk menghasilkan sebatian L. Tindak balas sebatian L dengan bromin, Brz dengan kehadiran ferum tribromida, FeBrs menghasilkan sebatian M. Benzena juga menjalani tindak balas alkilasi Fridel-crafts dengan kloroetana, CH3CH2CI dengan menggunakan pemangkin N untuk menghasilkan sebatian P. (i) Draw the structural formula of L, M and P. Lukiskan formula struktur bagi sebatian L, M dan P. (ii) State catalyst N. Nyatakan pemangkin N. (iii) Show the formation of electrophile that will be reacted with benzene for the formation of compound P.4G 4G ill iill 1:54 PM 43 ... H2NCH;CH,CHNH2 CH3 3. Draw structures corresponding to the following IUPAC names: (a) Triethylamine (b) N-Methylaniline (c) Tetraethylammonium bromide (e) N-Ethyl-N-methylcyclopentylamin (d) p-Bromoaniline