Barium sulfate from a 1.300-g sample was contaminated with 9.4 mg of Fe2(SO4)3 and weighed a total of 314.0 mg. Calculate a) the apparent percent BaSO4 (Apparent – the value of analyte concentration obtained when the interference is not considered) b) the true percent BaSO4
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- Barium sulfate from a 1.300-g sample was contaminated with 9.4 mg of Fe2(SO4)3 and weighed a total of 314.0 mg. Calculate
- a) the apparent percent BaSO4 (Apparent – the value of analyte concentration obtained when the interference is not considered)
- b) the true percent BaSO4
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- A 0.1475-M solution of Ba(OH)2 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. (See attached image)(a) Calculate the mean w/v percentage of acetic acid in the sample.(b) Calculate the standard deviation for the results.(c) Calculate the 90% confidence interval for the mean.(d) (d) At the 90% confidence level, could any of the results be discarded?Exactly 1.00 grams of granular table salt was dissolved in deionized water up to 500 mL. An aliquot of 20 mL was titrated with AgNO3 (T = 8244 mg/mL) and consumed 46.60 mL to reach end point. Calculate the percent purity of the NaCl. Ans in 2 sig figures.2+ as (6) A sample of an ore was analyzed for Cu* follows. A 1.25 g sample of the ore was dissolved in acid and diluted to volume in a 250 mL volumetric flask. A 20 mL portion of the resulting solution was transferred by pipet to a 50 ml volumetric flask and diluted to volume. An analysis showed that the concentration of 2+ Cu* in the final solution was 4.62 ppm. What is the weight percent of Cu in the original ore?
- 4.(a) Aqueous 50.5 % (w/w) sodium hydroxide has a density of 1.53 g cm–3. Calculate the concentration of this solution in mol dm–3. (b) What volume of 50.5 % (w/w) aqueous sodium hydroxide is required to prepare 500 cm3 of 0.100 mol dm–3 stock NaOH? [Start with your answer to 4(a)]A 0.1475-M solution of Ba(OH)2 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. (See attached image)(a) Calculate the mean w/v percentage of acetic acid in the sample.(b) Calculate the standard deviation for the results. (Take note if n-1 should be used)(c) Calculate the 90% confidence interval for the mean.(d) (d) At the 90% confidence level, could any of the results be discarded?A solution of Ba(OH)2 was standardized against0.1215 g of primary-standard-grade benzoic acid, C6H5COOH (122.12 g/mol). An end point was observedafter addition of 43.25 mL of base. (a) Calculate the molar concentration of the base. (b) Calculate the standard deviation of the molarconcentration if the standard deviation for themass measurement was ±0.3 mg and that for thevolume measurement was ±0.02 mL. (c) Assuming an error of ±0.3 mg in the mass measurement,calculate the absolute and relative systematicerror in the molar concentration.
- A 1.407 g sample of canned tuna was analyzed by the Kjeldahl method. The liberated NH3 required 26.45 mL of 0.1180 M HCl. Calculate the percentage nitrogen and protein in the sample. Assume that the protein factor is 6.25, i.e. % protein = % N x 6.25.A sample containing iron is approximately 99.0% w/w Fe. Using ammonia, iron is precipitated as Fe (OH)3 which is ignited to Fe203. (a) What is the gravimetric factor for analyte Fe (AW=55.85 g/mol) and precipitate Fe203 (FW=159.69 g/mol)? (b) What mass of sample is needed to ensure that the Fe203 precipitate would weigh at least 1.00 g?How many milliliters of 0.10 M Pb(NO 3 )2 should be used to make ni(en)(h2o)4so4 10% mole excess?
- Excess (NH4)2SO4 ( NH 4 ) 2 SO 4 was added to a 70.0 mL 70.0 mL solution containing BaCl2 BaCl 2 (MW=208.23 g/mol). ( MW = 208.23 g/mol ) . The resulting BaSO4 BaSO 4 (MW=233.43 g/mol) ( MW = 233.43 g/mol ) precipitate had a mass of 0.2192 g 0.2192 g after it was filtered and dried. What is the molarity of BaCl2 BaCl 2 in the solution?An impure sample of calcium carbonate with a mass of 7.95 g was reacted with 50.00 cm3 of 1.00 mol dm hydrochloric acid (an excess). The resulling solution was transferred to a volumetric flask and titrated with 11.10cm3 of 0.300 mol dm-3 sodium hydroxide solution. Determine the percentage purity by mass of the calcium carbonate sample.CaCO3 + HCl -> CaCl2 + H2O + CO2 HCl + NaOH -> NaCl +H2O a. Determine how many moles of hydrochloric acid were used.b. Determine how many moles of excess HCI was titratedc. Determine how much in moles calcium carbonate present in the sample.d. Calculate the mass of calcium carbonate presente. Determine the percentwge calcium carbonate is in the sample.How many milliliters of 0.05 M EDTA are required to react with the calcium and magnesium in a 0.1414 g sample that is 92.4% dolomite, CaCO3 · M9CO3 (FM: 184.4 g/mol)?