A sample of feldspar weighing 1.500g is decomposed, and eventually there is obtained a mixture of KCl and NaCl weighing 0.1801 g. These chlorides are dissolved in H2O, a 50-mL pipetful of 0.08333 N AGNO3 is added, and the precipitate is filtered off. The filtrate requires 16.47 mL of 0.1000N KCNS, with ferric alum as indicator. Calculate the percentage of K2O in the silicate.

A sample of feldspar weighing 1.500g is decomposed, and eventually there is obtained a mixture of KCl and NaCl weighing 0.1801 g. These chlorides are dissolved in H2O, a 50-mL pipetful of 0.08333 N AGNO3 is added, and the precipitate is filtered off. The filtrate requires 16.47 mL of 0.1000N KCNS, with ferric alum as indicator. Calculate the percentage of K2O in the silicate.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section20.3: Copper: A Coinage Metal

Problem 20.4E

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1. A sample of feldspar weighing 1.500g is decomposed, and eventually there is obtained a mixture of KCI and NaCi weighing 0.1801 g. These chlorides are dissolved in H20, a 50-mL pipetful of 0.08333 N AGNO3 is added, and the precipitate is filtered off. The filtrate requires 16.47 mL of 0.100ON KCNS, with ferric alum as indicator. Calculate the percentage of K20 in the silicate.
A 0.4852g sample of an iron ore was dissolved in acid to the 3+ state, then precipitated as Fe2O3 x H2O. The pp was filtered, washed and calcined to Fe2O3, which gave a weight of 0.2481g. Calculate the Fe % in the sample.
(a) What is the percentage of MnO, in a pyrolusite ore if a sample weighing 0.4000 g is treated with a 0.6000 g of pure H2C2O4.2H20 and dilute H,SO4 and after reduction has taken place (MnO2 + H2C204 + 2H* → Mn2+ + 2CO, + 2H,O), the excess oxalic acid requires 26.26 mL of 0.1000 N KMnO4 for titration? (b) If pure As,03 were used instead of oxalic acid, how many grams would be required in order for the other numerical data to remain the same?
1. A 0.9882 gram sample of iron ore is dissolved, the iron reduced to Fe2+, and the solution was titrated with 36.40 mL of 0.02065 M KMnO4 in acid solution. (a) Write the titration reaction. (b) Calculate the %FeO (M.M. = 71.85) in the sample. 2. A sample of primary standard grade K2Cr2O7 (MM = 294.20) weighing 0.2153 g is dissolved, the solution acidified and excess KI added. The liberated I2 requires 44.86 mL of the Na2S2O3 for titration. (a) Write the titration reaction. (b) Calculate the molarity of the titrant solution.
1. A 0.9882 gram sample of iron ore is dissolved, the iron reduced to Fe2+, and the solution was titrated with 36.40 mL of 0.02065 M KMnO4 in acid solution. (a) Write the titration reaction. (b) Calculate the %FeO (M.M. = 71.85) in the sample. 2. A sample of primary standard grade K2Cr2O7 (MM = 294.20) weighing 0.2153 g is dissolved, the solution acidified and excess KI added. The liberated I2 requires 44.86 mL of the Na2S2O3 for titration. (a) Write the titration reaction. (b) Calculate the molarity of the titrant solution. Box the final answer.
A sample of steel weighing 2.00 g is analyzed for Cr (AW 52.0). The Cr is oxidized into chromate with alkaline permanganate and the excess permanganate is destroyed. A certain volume of 0.120 M FeSO, is added to the acid solution and the excess is titrated with 0.0220 M KMNO4, requiring 31.0 mL. If the sample contained 0.50 % Cr, what volume (in mL) of FeSO, was added?
World production of chromite (FeCr₂O₄), the main ore ofchromium, was 1.5107metric tons in 2003. To isolate chro-mium, a mixture of chromite and sodium carbonate is heated inair to form sodium chromate, iron(III) oxide, and carbon diox-ide. The sodium chromate is dissolved in water, and this solutionis acidified with sulfuric acid to produce the less soluble sodiumdichromate. The sodium dichromate is filtered out and reduced with carbon to produce chromium(III) oxide, sodium carbonate,and carbon monoxide. The chromium(III) oxide is then reduced to chromium with aluminum metal. (a) Write balanced equations for each step. (b) What mass of chromium (in kg) could be pre-pared from the 2003 world production of chromite?
A sample of steel weighing 2.00 g is analyzed for Cr (AW 52.0). The Cr is oxidized into chromate with alkaline permanganate and the excess permanganate is destroyed. A certain volume of 0.120 M FeSO4 is added to the acid solution and the excess is titrated with 0.0220 M KMnO4, requiring 31.0 mL. If the sample contained 0.50 % Cr, what volume (in mL) of FeSO4 was added?
A 0.8040 gram sample of an iron ore is dissolved in acid. The iron is then reduced to Fe2+ and titrated with 47.22 mL of 0.02242 M KMnO4 solution. What is the wt% Fe3O4 in the ore sample?
(a) What is the percentage of MnO2 in a pyrolusite ore if a sample weighing 0.4000g is treated with 0.6000g of pure H2C2O4•2H2O and dilute H2SO4 and after reduction has taken place (MnO2 + H2C2O4 + 2H+→ Mn2++ 2CO2 + 2H2O), the excess oxalic acid requires 26.26ml of 0.1000N KMnO4 for titration? (b) If pure As2O3 were used instead of oxalic acid, how many grams would be required in order for the other numerical data to remain the same?
4. From a pyrite concentrate containing 65% by weight pyrite (FeS,) by total oxdizer roasting, the following Fe,03 is produced according to the reaction. 5 tons of pyrite concentrate is reasted daily (MA, g/ mol; Fe 56; S: 32; O: 16; H: 1). 2FES2+11/20, Fe,03 + 450, If it is desired to produce 95% sulfuric acid from the flue gases, how much sulfuric acid by volume is produced in 1 day? (d.atunk anste 95%: 1.84 g/ cm2)
The Fe2+Fe2+ (55.84555.845 g/mol) content of a 2.2472.247 g steel sample dissolved in 50.0050.00 mL of an acidic solution was determined by tiration with a standardized 0.1200.120 M potassium permanganate (KMnO4KMnO4, 158.034158.034 g/mol) solution. The titration required 29.2929.29 mL to reach the end point. What is the concentration of iron in the steel sample? Express your answer as grams of FeFe per gram of steel. MnO−4+8H++5Fe2+↽−−⇀Mn2++5Fe3++4H2OMnO4−+8H++5Fe2+↽−−⇀Mn2++5Fe3++4H2O concentration: g Fe/g steel (please type answer not write by hend)