6. (McQuarrie 5-26) Show that (x²) = [*° 42(x)*x²+2(x)dx = 5 h = 2 √μk for a harmonic oscillator. The square root of (x²) is the root-mean-square-displacement of the oscillator. 7. (McQuarrie 5-27) Show that (p) = 0 and {p²) = [ ¢2(x)*P²v2(x)dx = {2ħ√/µk for a harmonic oscillator.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
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Chapter18: Raman Spectroscopy
Section: Chapter Questions
Problem 18.5QAP
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6. (McQuarrie 5-26) Show that
(x²) = [*° 42(x)*x²+2(x)dx =
5 h
=
2 √μk
for a harmonic oscillator. The square root of (x²) is the root-mean-square-displacement of
the oscillator.
7. (McQuarrie 5-27) Show that (p) = 0 and
{p²) = [ ¢2(x)*P²v2(x)dx = {2ħ√/µk
for a harmonic oscillator.
Transcribed Image Text:6. (McQuarrie 5-26) Show that (x²) = [*° 42(x)*x²+2(x)dx = 5 h = 2 √μk for a harmonic oscillator. The square root of (x²) is the root-mean-square-displacement of the oscillator. 7. (McQuarrie 5-27) Show that (p) = 0 and {p²) = [ ¢2(x)*P²v2(x)dx = {2ħ√/µk for a harmonic oscillator.
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