5. In the Dumas method for determining the molar mass of an unknown volatile liquid, a sample of a volatile liquid that boils below 100°C is vaporized in a boiling water bath and the mass of the vapor required to fill the flask is determined. The following data was collected: Flask Volume Mass of Flask + Cap Mass of Flask+ Condensed Liquid Mass of Condensed Liquid Temperature of Water Bath (C) Barometric Pressure (atm) 100.0 + 100.0 + 79.6 mL 279.6 mL 143.85 g 144.95 g 1,10 g 84.1 °C 0.985 atm a. What is the molar mass of the unknown? b. What will its temperature be when the pressure is 1.20 atm and the volume is 250.0 mL? P

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter9: Liquids And Solids
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5. In the Dumas method for determining the molar mass of an unknown volatile liquid,
a sample of a volatile liquid that boils below 100°C is vaporized in a boiling water bath
$
(4 101
and the mass of the vapor required to fill the flask is determined. The following data
was collected:
Flask Volume
Mass of Flask + Cap
Mass of Flask + Condensed Liquid
Mass of Condensed Liquid.
Temperature of Water Bath [°C)
Barometric Pressure (atm)
Accessibility: Unavailable
15
a. What is the molar mass of the unknown?
b. What will its temperature be when the pressure is 1.20 atm and the volume is
250.0 mL?
EN
100.0 100.0 + 79.6 mL = 279.6 mL
143.85 g
144.95 g
&
1.10 g
84.1 °C
0.985 atm
CH
8
144
9
ho 11
O
Transcribed Image Text:5. In the Dumas method for determining the molar mass of an unknown volatile liquid, a sample of a volatile liquid that boils below 100°C is vaporized in a boiling water bath $ (4 101 and the mass of the vapor required to fill the flask is determined. The following data was collected: Flask Volume Mass of Flask + Cap Mass of Flask + Condensed Liquid Mass of Condensed Liquid. Temperature of Water Bath [°C) Barometric Pressure (atm) Accessibility: Unavailable 15 a. What is the molar mass of the unknown? b. What will its temperature be when the pressure is 1.20 atm and the volume is 250.0 mL? EN 100.0 100.0 + 79.6 mL = 279.6 mL 143.85 g 144.95 g & 1.10 g 84.1 °C 0.985 atm CH 8 144 9 ho 11 O
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