4. For the following reactions, develop a transition-state structure using molecular models which would account for the observed stereoselectivity. Also, describe the type of pericyclic reactions using the proper terminology. (each Br Ayon A Br heat 0°℃ heat heat d) MeO₂C OCH3 OCH3 heat •do-goo HO НО heat MeO₂C A CO₂Me CO₂Me product?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
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4. For the following reactions, develop a transition-state structure using molecular models which would account for the
observed stereoselectivity. Also, describe the type of pericyclic reactions using the proper terminology. (each
Br
heat
A &
Br
b)
F 0°C
F
heat
heat
d)
product?
=& &
MeO₂C
OCH3
H
HO
1.
CO₂Me
مر
CO₂Me
LOCH3 heat
heat MeO₂C
HO
Transcribed Image Text:4. For the following reactions, develop a transition-state structure using molecular models which would account for the observed stereoselectivity. Also, describe the type of pericyclic reactions using the proper terminology. (each Br heat A & Br b) F 0°C F heat heat d) product? =& & MeO₂C OCH3 H HO 1. CO₂Me مر CO₂Me LOCH3 heat heat MeO₂C HO
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