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- Draw the keto form of the following enol.Draw the structures A, B and C for the reaction sequence below. Dehydration via an E1cb mechanism Michael Reaction Intramolecular Aldol Reaction A В КОН /ETOH / heat C КОН /ETOH КОН /ETOHFor the following reaction: H NaOH CH3CH₂OH a Draw the major organic product, assuming no dehydration of aldol product has occurred. ? ChemDoodleⓇ
- Draw the major product of the aldol addition reaction. Ignore inorganic byproducts. I H H Q 1. NaOH 2. Neutralizing work-up Ato Drawing ar Draw dWhat aldehyde or ketone is needed to prepare each compound by an aldol reaction?Please complete this synthesis with an epoxide. Please draw it out and wxplqin each step. C HO NH₂
- H 1 2 CH3 3 CH3 4 NaOH aldol product onlyWhat is the product formed when each dicarbonyl compound undergoes an intramolecular aldol reaction, followed by dehydration.Draw the structure of the major aldol product (prior to possible dehydration) of the following reaction. O ⇐ H dilute NaOH 95% aq. ethanol, 0-5° • You do not have to consider stereochemistry. •If no reaction occurs, draw the organic starting material. + HO CH3 On t ?
- Draw the major product of the following reaction sequence. OH H2CrO4 HO NaBH4 H*/H20 ELOH он H3C* ноWhat functional group is formed as the final product of an aldol condensation? A. B-hydroxycarbonyl В. a,B-unsaturated carbonyl C. enol D. enolate2 H3C H3C H C→XT OH H3C The aldol reaction is a carbonyl condensation reaction between two carbonyl partners and involves a combination of nucleophilic addition and a-substitution steps. One partner is converted into an enolate ion nucleophile and adds to the electrophilic carbonyl group of the second partner. In the classic aldol reaction, the carbonyl partners are aldehydes or ketones, although aldehydes are more reactive. The product is a ß-hydroxy carbonyl compound. base :0: OH H H Under reaction conditions slightly more vigorous than those employed for the aldol reaction, the ß-hydroxyl group is eliminated in an E1cB dehydration to give an a,ß-unsaturated carbonyl compound. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instruct ns H3C heat OH H3C :0: H + H₂O H