21.0 mL of 0.127 M diprotic acid (H2A) was titrated with 0.1019 M KOH. The acid ionization constants for the acid are Ka1=5.2×10-5 and Ka2=3.4×10-10. A)At what added volume of base does the first equivalence point occur? B)At what added volume of base does the second equivalence point occur?
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Check out a sample Q&A here- Fifty cm3 of 1.000 M nitrous acid is titrated with 0.850 M NaOH. What is the pH of the solution (a) before any NaOH is added? (b) at half-neutralization? (c) at the equivalence point? (d) when 0.10 mL less than the volume of NaOH to reach the equivalence point is added? (e) when 0.10 mL more than the volume of NaOH to reach the equivalence point is added? (f) Use your data to construct a plot similar to that shown in Figure 14.10 (pH versus volume NaOH added).Two acids, each approximately 0.01 M in concentration, are titrated separately with a strong base. The adds show the following pH values at the equivalence point: HA, pH = 9.5, and HB, pH = 8.5. (a) Which is the stronger acid, HA or HB? (b) Which of the conjugate bases, A or B, is the stronger base?Calculate the pH change when 10.0 mL of 0.100-M NaOH is added to 90.0 mL pure water, and compare the pH change with that when the same amount of NaOH solution is added to 90.0 mL of a buffer consisting of 1.00-M NH3 and 1.00-M NH4Cl. Assume that the volumes are additive. Kb of NH3 = 1.8 × 10-5.
- The titration curves for two acids with the same base are shown on this graph. (a) Which is the curve for the weaker acid? Explain your choice. (b) Give the approximate pH at the equivalence point for the titration of each acid. (c) Explain why the pH at the equivalence point differs for each acid. (d) Explain why the starting pH values of the two acids differ. (e) Which indicator or indicators, phenolphthalein, bromthymol blue, or methyl red, could be used for the titration of Acid 1? For the titration of Acid 2? Explain your choices.When 40.00 mL of a weak monoprotic acid solution is titrated with 0.100-M NaOH, the equivalence point is reached when 35.00 mL base has been added. After 20.00 mL NaOH solution has been added, the titration mixture has a pH of 5.75. Calculate the ionization constant of the acid.Marble is almost pure CaCO3. Acid rain has a devastating effect on marble statuary left outdoors. Assume that the reaction which occurs is CoCO3(s)+ H+(aq)Ca2+(aq)+HCO3(aq) Neglecting all other competing equilibria and using Tables 15.1 and 13.2, calculate (a) K for the reaction. (b) the molar solubility of CaCO3 in pure water. (c) the molar solubility of CaCO3 in acid rainwater with a pH of 4.00.
- The following plot shows the pH curves for the titrations of various acids by 0.10 M NaOH (all of the acids were 50.0-mL samples of 0.10 M concentration). a. Which pH curve corresponds to the weakest acid? b. Which pH curve corresponds to the strongest acid? Which point on the pH curve would you examine to see if this acid is a strong acid or a weak acid (assuming you did not know the initial concentration of the acid)? c. Which pH curve corresponds to an acid with Ka 1 106?Consider the following pH curves for 100.0 mL of two different acids with the same initial concentration each titrated by 0.10 M NaOH. a. Which plot represents a pH curve of a weak acid, and which plot is for a strong acid? How can you tell? Cite three differences between the plots that help you decide. b. In both cases the pH is relatively constant before the pH changes greatly. Does this mean that at some point in each titration each solution was a buffered solution? c. True or false? The equivalence point volume for each titration is the same. Explain your answer. d. True or false? The pH at the equivalence point for each titration is the same. Explain your answer.A sample of 0.220 M triethylamine, (CH3CH2)3 N, is titrated with 0.544 M HCl. (K b (CH3CH2)3N=5.2104) (a) Write a balanced net ionic equation for the titration. (b) How many milliliters of HCl are required to reach the equivalence point? (c) Calculate [(CH3CH2)3N], [(CH3CH2)3NH+], [H+], and [Cl-] at the equivalence point. (Assume that volumes are additive.) (d) What is the pH at the equivalence point?
- An acid-base titration was used to find the percentage of NaHCO3 in 0.310 g of a powdered commercial product used to relieve upset stomachs. The titration required 14.3 mL of 0.101-M HCl to titrate the powder to the equivalence point. Assume that the NaHCO3 in the powder is the only substance that reacted with the titrant. Calculate the percentage of NaHCO3 in the powder.Each of the solutions in the table has the same volume and the same concentration, 0.1 M. Which solution requires the greatest volume of 0.1-M NaOH to titrate to the equivalence point? Explain your answer.Consider the following titration curves. The solution in the buret is 0.1 M. The solution in the beaker has a volume of 50.0 mL. Answer the following questions. (a) Is the titrating agent (solution in the buret) an acid or a base? (b) Which curve shows the titration of the weakest base? (c) What is the Ka of the conjugate acid of the base titrated in curve B? (d) What is the molarity of the solution in the beaker for curve C? (e) What is the pH at the equivalence point for curve A?