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2. The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg2Cl2 that precipitate per liter per minute. The data obtained are listed in the table. 2 HgCl2(aq) + C2042-(aq) → 2 C(aq) + 2 CO2(g) + Hg:Cl2(s) Experiment [HgCl2] (M) [C2O42-] (M) Initial rate (mol L-1 min-1) 1 0.105 0.15 1.8×10-5 0.105 0.30 7.1x10-5 0.052 0.30 3.5x10-5 4 0.052 0.15 8.9x10-6 (a) Determine the order of reaction with respect to HgCl2, with respect to C2O4²- and overall. (b) What is the value of the rate constant k? (c) What would be the initial rate of reaction if [HgCl2] = 0.094 M and [C2O42-] = 0.19 M? %3D

2. The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg2Cl2 that precipitate per liter per minute. The data obtained are listed in the table. 2 HgCl2(aq) + C2042-(aq) → 2 C(aq) + 2 CO2(g) + Hg:Cl2(s) Experiment [HgCl2] (M) [C2O42-] (M) Initial rate (mol L-1 min-1) 1 0.105 0.15 1.8×10-5 0.105 0.30 7.1x10-5 0.052 0.30 3.5x10-5 4 0.052 0.15 8.9x10-6 (a) Determine the order of reaction with respect to HgCl2, with respect to C2O4²- and overall. (b) What is the value of the rate constant k? (c) What would be the initial rate of reaction if [HgCl2] = 0.094 M and [C2O42-] = 0.19 M? %3D

Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter7: Reaction Rates And Chemical Equilibrium
Section: Chapter Questions
Problem 7.65P
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The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg2Cl2 that precipitate per liter per minute. The data obtained are listed in the table.

2. The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg2Cl2 that precipitate per liter per minute. The data obtained are listed in the table. 2 HgCl2(aq) + C204² (aq) → 2 CI (aq) + 2 CO2(g) + Hg2Cl2(s) Experiment [HgCl2] (M) [C2O42-] (M) Initial rate (mol L-1 min-1) 1 0.105 0.15 1.8×10-5 2 0.105 0.30 7.1×10-5 0.052 0.30 3.5x10-5 4 0.052 0.15 8.9×10-6 (a) Determine the order of reaction with respect to HgCl2, with respect to C2O4² and overall. (b) What is the value of the rate constant k? (c) What would be the initial rate of reaction if [HgCl2] = 0.094 M and [C:O:?-] = 0.19 M? %3D
Transcribed Image Text:2. The rate of the following reaction in aqueous solution is monitored by measuring the number of moles of Hg2Cl2 that precipitate per liter per minute. The data obtained are listed in the table. 2 HgCl2(aq) + C204² (aq) → 2 CI (aq) + 2 CO2(g) + Hg2Cl2(s) Experiment [HgCl2] (M) [C2O42-] (M) Initial rate (mol L-1 min-1) 1 0.105 0.15 1.8×10-5 2 0.105 0.30 7.1×10-5 0.052 0.30 3.5x10-5 4 0.052 0.15 8.9×10-6 (a) Determine the order of reaction with respect to HgCl2, with respect to C2O4² and overall. (b) What is the value of the rate constant k? (c) What would be the initial rate of reaction if [HgCl2] = 0.094 M and [C:O:?-] = 0.19 M? %3D
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