15. What is the product, W, of the following reaction sequence? 1 equiv. I -COzH i. excess NaOEt ii. Br IV 1 equiv. HO₂C. OH Br II iii H₂O heat CO₂H D-CO,H V W COOH III
15. What is the product, W, of the following reaction sequence? 1 equiv. I -COzH i. excess NaOEt ii. Br IV 1 equiv. HO₂C. OH Br II iii H₂O heat CO₂H D-CO,H V W COOH III
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter18: Electrochemistry
Section: Chapter Questions
Problem 9RQ: What characterizes an electrolytic cell? What is an ampere? When the current applied to an...
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![15. What is the product, W, of the following reaction
sequence?
1 equiv.
I
COzH
i. excess NaOEt
ii. Bri
IV
1 equiv.
HO₂C.
OH
Br
II
IV
17. Predict the product of the following
reaction sequence.
i. NaOC₂H5
ii. CH3CH₂CH₂Br
iii. NaOH
iv. H3O*, heat
iii H30
heat
CO₂H
OH
?
CO₂H
OH
Ju qe je
OH
O
I
II
III
V
W
COOH
III
16. What would be the major
product of the following reaction
sequence?
OH
a)
Ethyl acetoacetate
b)
Ethyl acetoacetate
c)
Ethyl acetoacetate
IV
e)
Ethyl hexanoate
PCC
CH₂Cl₂
18. 2-Heptanone can be synthesized by
which reaction sequence?
heat,
II
NaOEt CH3(CH₂) 3 Br
EtOH
NaOEt
EtOH
i. dil.OH heat
ii. H30
d)
Ethyl acetoacetate CH₂(CH₂);Br_
i. LDA
ii. C₂H₂I
22
i. NaOEt, EtOH
ii. CH3COCI
V
III
NaOEt
EtOH
i. dil.OH heat
ii. H30
CH3(CH₂)3Br
CH₂(CH₂), Br
i. dil.OH
ii. H30¹
heat,
i. dil.OH heat_
ii. H30*](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fae4237e8-0a91-4962-8db1-4f59bb0866b5%2Fe768523f-4fc6-477c-b54b-d0c80b309ca7%2Ftl00ocdl_processed.jpeg&w=3840&q=75)
Transcribed Image Text:15. What is the product, W, of the following reaction
sequence?
1 equiv.
I
COzH
i. excess NaOEt
ii. Bri
IV
1 equiv.
HO₂C.
OH
Br
II
IV
17. Predict the product of the following
reaction sequence.
i. NaOC₂H5
ii. CH3CH₂CH₂Br
iii. NaOH
iv. H3O*, heat
iii H30
heat
CO₂H
OH
?
CO₂H
OH
Ju qe je
OH
O
I
II
III
V
W
COOH
III
16. What would be the major
product of the following reaction
sequence?
OH
a)
Ethyl acetoacetate
b)
Ethyl acetoacetate
c)
Ethyl acetoacetate
IV
e)
Ethyl hexanoate
PCC
CH₂Cl₂
18. 2-Heptanone can be synthesized by
which reaction sequence?
heat,
II
NaOEt CH3(CH₂) 3 Br
EtOH
NaOEt
EtOH
i. dil.OH heat
ii. H30
d)
Ethyl acetoacetate CH₂(CH₂);Br_
i. LDA
ii. C₂H₂I
22
i. NaOEt, EtOH
ii. CH3COCI
V
III
NaOEt
EtOH
i. dil.OH heat
ii. H30
CH3(CH₂)3Br
CH₂(CH₂), Br
i. dil.OH
ii. H30¹
heat,
i. dil.OH heat_
ii. H30*
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